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tert-Butylamine

2-Methylpropan-2-amine · CAS 75-64-9

The fully branched member of the butylamine family, with three very different downstream destinies: tert-butylamine is the precursor to sulfenamide rubber accelerators, triazine pesticides, and the pharmaceutical counterion known as erbumine.

Chelora Chemicals supplies tert-butylamine to rubber-chemical, agrochemical and pharmaceutical-intermediate manufacturers worldwide, with full GHS documentation on every consignment.

  • Sulfenamide rubber accelerator precursor
  • Triazine pesticide intermediate
  • Erbumine pharma counterion
  • Fully branched amine
  • Flammable & corrosive — handle accordingly
  • UN 3286 · Class 3 (8)

Product identity

CAS Number
75-64-9
IUPAC name
2-Methylpropan-2-amine
Molecular formula
C₄H₁₁N
Molecular weight
73.14 g/mol
Boiling point
43 – 47 °C
UN Number
3286
SMILES
CC(C)(C)N
HS Code
2921 19*

* Confirm the current HS classification and import regulatory status for your destination with your own regulatory affairs team.

73.14g/mol molecular weight
43 – 47 °CBoiling point
99%+Typical assay
Class 3 (8)Flammable liquid, corrosive
Product overview

What tert-Butylamine is used for

tert-Butylamine is a colourless liquid with a fishy/ammoniacal odour, fully miscible with water. It is the fully branched member of the C4 butylamine isomer family — the amine nitrogen sits on a carbon bonded to three methyl groups, making it structurally distinct from its three siblings.

That structure feeds three quite different downstream industries. It is the precursor to sulfenamide rubber-vulcanization accelerators such as TBBS (N-tert-butyl-2-benzothiazylsulfenamide), which controls the rate of rubber vulcanization. It is also the building block for a family of triazine pesticides including terbacil, terbutryn and terbumeton. And in pharmaceutical chemistry, it supplies the counterion known as erbumine, used to form stable salts with active pharmaceutical ingredients — most notably perindopril erbumine, an ACE-inhibitor blood-pressure medication.

Where it sits among the butylamines

  • n-Butylamine straight-chain, a broad-spectrum intermediate. See that page.
  • Isobutylamine branched at the carbon adjacent to the amine. See that page.
  • sec-Butylamine amine on the second carbon, notable as a direct-use fungicide. See that page.
  • tert-Butylamine (this product) fully branched at the amine-bearing carbon.

Appearance and handling character

tert-Butylamine is highly flammable and corrosive, with a boiling point close to body temperature, meaning headspace vapour pressure is a real handling consideration even at moderate ambient temperatures.

Typical commercial specification
ParameterTypical value
AppearanceColourless liquid, fishy/ammoniacal odour
Assay99.0% min
Water content0.3% max
Colour (Hazen)20 max
Non-volatile residue0.05% max

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateLiquid at room temperature
Boiling point43 – 47 °C
Melting point-67.50 °C
Density (20 °C)0.696 g/mL
Water solubilityFully miscible
BasicityStrong base, typical of primary alkylamines

Physical constants compiled from public reference data for CAS 75-64-9 and rounded for readability. Treat them as orientation, not as a specification.

Applications

Where our customers put this amine to work

One fully branched amine, three quite different industries.

Sulfenamide rubber accelerators

Precursor to TBBS and related sulfenamide accelerators that control rubber-vulcanization rate.

  • Technical-grade specification
  • Bulk tonnage supply available
  • Technical desk review on request

Triazine pesticide synthesis

Building block for terbacil, terbutryn and terbumeton among other triazine herbicides.

  • Multiple pack sizes available
  • Full analytical documentation
  • Contracted seasonal tonnage available

Pharmaceutical counterion (erbumine)

Forms stable salts with active pharmaceutical ingredients, as in perindopril erbumine.

  • Pharma-grade documentation available
  • Contracted annual tonnage supported
  • Technical desk review on request

General organic synthesis

A versatile branched primary amine for method development and process research across specialty chemistry.

  • Research and process-scale quantities
  • High-purity grade available on request
  • Technical documentation supplied

Research & analytical use

Small liquid quantities for method development and process research.

  • Packs from 1 L / 5 L
  • Full analytical documentation available
  • Retained sample held against the lot

Contract & scheduled supply

Rubber-chemical and agrochemical producers running continuous consumption are supported with scheduled call-off tonnage.

  • Annual contracts with scheduled call-off
  • Price held across the contract period
  • Second source held in reserve
Buying from Chelora

How we supply tert-Butylamine

Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. With four butylamine isomers in common commercial use, and downstream chemistry spanning rubber, agrochemical and pharmaceutical sectors, getting the right grade matched to your end use is the first thing we check.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window.

We keep a second qualified source on this line, so a single-plant disruption never becomes your production problem.

  • Isomer confirmed before we quote. n-, iso-, sec- and tert-butylamine are not interchangeable in downstream chemistry.
  • Grade matched to end use. Pharmaceutical-intermediate orders carry different documentation needs than rubber-chemical or agrochemical orders.
  • Dangerous-goods documentation filed correctly. Class 3 with a Class 8 subsidiary risk needs both hazard sets declared accurately.
  • Scheduled call-off scheduling. We hold contracted tonnage and release it against your production calendar.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
  • Export machinery handled in-house. Classification, approved packing, labelling, freight booking and customs paperwork are ours to manage.
Packing & logistics

Packed the way your plant receives it

Drum, IBC or bulk — tell us your preferred format and we will quote and classify to it.

Drums

200 L / 55 USG

Standard UN-approved steel drums for corrosive flammable liquids, the usual choice for most orders.

IBCs

Intermediate bulk containers

For mid-volume orders where drum handling becomes a logistics burden.

ISO tank / bulk

High-volume contracts

Bulk liquid transport for continuous-consumption customers on long-term supply agreements.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with dangerous-goods documentation filed before booking.

1 L / 5 L packs

Trial / sample quantities

Small packs dispatched for process trials before a commercial order is placed.

Scheduled release

Contracted call-off supply

We hold contracted tonnage and release it against your production calendar.

Safety, storage & handling

Flammable, corrosive, and toxic if inhaled

tert-Butylamine's low boiling point makes vapour-ignition control a central handling concern. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Danger

Classified hazards

  • H225Highly flammable liquid and vapour.
  • H302Harmful if swallowed.
  • H314Causes severe skin burns and eye damage.
  • H331Toxic if inhaled.

Always read the SDS issued with your specific batch. Handle with chemical-resistant gloves, splash goggles, and respiratory protection where ventilation is limited.

Storage

Store in tightly closed, corrosion-resistant containers in a cool, well-ventilated area away from heat, sparks, open flame and oxidisers. The low boiling point means headspace vapour pressure must be managed even at moderate ambient temperatures.

Handling

Use with local exhaust ventilation and appropriate respiratory protection. Ground and bond containers during transfer to control static discharge. Avoid skin and eye contact; have emergency eyewash and safety-shower provision nearby.

Transport

Ships as UN 3286, typically Class 3 (flammable liquid) with a Class 8 (corrosive) subsidiary risk. We confirm and document packing group and exact classification for your specific shipment and destination.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Assay and water content confirmed against your process requirement before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and dangerous-goods paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How tert-butylamine is made

tert-Butylamine is produced industrially by the catalytic amination of isobutylene (or tert-butanol) with ammonia over a suitable catalyst — a standard, well-established industrial route for this fully branched primary alkylamine.

We do not publish operating process parameters here; this is background only. Full technical and safety documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familyPrimary aliphatic amine, fully branched (C4)
Basic characterStrong base, typical of primary alkylamines
ReactivityNucleophilic nitrogen; forms sulfenamides, triazine derivatives and pharmaceutical salts
Structural isomersn-Butylamine, isobutylamine, sec-butylamine
Frequently asked

tert-Butylamine, answered

What is tert-butylamine used for?
Mainly as the precursor to sulfenamide rubber-vulcanization accelerators such as TBBS (N-tert-butyl-2-benzothiazylsulfenamide), to triazine pesticides including terbacil, terbutryn and terbumeton, and as the pharmaceutical counterion known as erbumine, used in salts such as perindopril erbumine.
What is erbumine?
Erbumine is the pharmaceutical name for the tert-butylamine counterion when it is used as a salt-forming agent with an active pharmaceutical ingredient, as in perindopril erbumine, an ACE-inhibitor blood-pressure medication.
Is tert-butylamine hazardous?
Yes. It is classified as a highly flammable liquid, harmful if swallowed, causes severe skin burns and eye damage, and is toxic if inhaled. Full GHS documentation accompanies every consignment.
What is the UN transport classification?
tert-Butylamine ships as UN 3286, typically Class 3 (flammable liquid) with a Class 8 (corrosive) subsidiary risk. We confirm and document the correct classification for your specific shipment.
What grade do you supply?
Technical grade, typically 99%+ assay. Tell us your end use and we will quote against the correct specification.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
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