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Isoprene

Isoprene · CAS 78-79-5

The monomer behind synthetic natural rubber — polymerised into cis-1,4-polyisoprene, and copolymerised into butyl rubber and SIS block copolymers.

Chelora Chemicals supplies inhibitor-stabilised isoprene to rubber and adhesive producers worldwide, with full documentation on every consignment.

  • Synthetic polyisoprene rubber
  • Butyl rubber comonomer
  • SIS block copolymers
  • Extremely flammable liquid
  • Suspected carcinogen
  • UN 1218

Product identity

CAS Number
78-79-5
IUPAC name
2-Methylbuta-1,3-diene
Molecular formula
C₅H₈
Molecular weight
68.12 g/mol
Boiling point
34.0 °C
Melting point
-146 °C
UN Number
UN 1218
HS Code
2901 24

Note: Isoprene is shipped stabilised with a polymerisation inhibitor; its low boiling point means it is handled as a cool, volatile liquid. Confirm requirements with your regulatory affairs team.

68.12g/mol molecular weight
34.0 °CBoiling point
0.681g/cm³ density
Volatile liquidPhysical state
Product overview

What Isoprene is used for

Isoprene is a colourless, highly volatile, flammable liquid with a mild, pungent odour, boiling just above room temperature. It is the five-carbon conjugated diene that forms the structural repeat unit of natural rubber, and is produced industrially mainly as a C5 co-product of ethylene steam cracking, extracted from pyrolysis gasoline.

Isoprene's single largest use is as the monomer for synthetic cis-1,4-polyisoprene rubber, a close structural match to natural rubber used in tyres, footwear and mechanical rubber goods. It is also copolymerised in small fractions with isobutylene into butyl rubber, and with styrene into styrene-isoprene-styrene (SIS) block copolymers used in pressure-sensitive adhesives and sealants.

Where it sits in the petrochemical value chain

  • Ethylene steam cracking the source of the C5 pyrolysis-gasoline stream that isoprene is extracted from.
  • Isoprene (this product) the diene monomer for the rubber and copolymer chains below.
  • Polyisoprene / Butyl Rubber / SIS downstream rubber and block-copolymer chains built on this monomer. See Isobutylene.

Handling character

Isoprene is extremely flammable, volatile, and a suspected human carcinogen, requiring inhibitor stabilisation and careful temperature control. Full hazard detail is in the Safety section below.

Typical commercial specification
ParameterTypical value
AppearanceColourless, volatile liquid
Assay99.0% min (polymer grade)
Dimer/peroxide contentWithin producer specification
Inhibitor (TBC) contentWithin producer specification

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateColourless, highly volatile, flammable liquid
Boiling point34.0 °C
Melting point-146 °C
Density0.681 g/cm³
Water solubilitySlightly soluble (~641 mg/L)
Flash point-54 °C (extremely flammable)

Physical constants compiled from public reference data for CAS 78-79-5 and rounded for readability. Treat them as orientation, not as a specification.

Applications

Where our customers put Isoprene to work

The diene behind synthetic natural rubber, butyl rubber and performance adhesives.

Synthetic polyisoprene rubber

Polymerised into cis-1,4-polyisoprene, a close match to natural rubber for tyres and mechanical goods.

  • Polymer-grade specification
  • Inhibited bulk & drum supply
  • Technical desk review on request

Butyl rubber comonomer

Copolymerised in small fractions with isobutylene into butyl rubber for innertubes and seals.

  • Industrial-grade specification
  • Documented batch traceability
  • Contract & spot supply

SIS block copolymers

Copolymerised with styrene into SIS thermoplastic elastomers for adhesives and sealants.

  • Full analytical documentation available
  • Retained sample held against the lot

Footwear & latex

Polyisoprene latex used in footwear soles, gloves and dipped-rubber goods.

  • Documented batch traceability
  • Technical desk review on request

Fine-chemical synthesis

Feedstock for terpenoid and fragrance-chemical synthesis in smaller volumes.

  • Research & process-scale quantities
  • Full documentation supplied

Contract & scheduled supply

Rubber and adhesive plants running continuous consumption are supported with scheduled bulk delivery.

  • Annual contracts with scheduled call-off
  • Price held across the contract period
  • Second source held in reserve
Buying from Chelora

How we supply Isoprene

Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. Isoprene's volatility and peroxide-formation tendency make inhibitor level and cold-chain logistics critical — that shapes how we manage this line.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window, and confirm your jurisdiction's import requirements before booking.

We keep a second qualified source on this line, so a single-plant disruption never becomes your production problem.

  • Inhibitor and dimer/peroxide levels confirmed before we quote. Consistency matters to downstream polyisoprene and butyl-rubber polymerisation.
  • UN 1218 documentation managed end to end. Classification, labelling and carrier compliance confirmed before booking.
  • Temperature-controlled logistics arranged where needed. Isoprene's low boiling point means cool-chain handling matters for quality retention.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
  • Export machinery handled in-house. Classification, approved packing, labelling, freight booking and customs paperwork are ours to manage.
  • Polymer-grade material sourced to your process. Matched precisely to your rubber or block-copolymer specification.
Packing & logistics

Packed the way your plant receives it

Drum, tote or bulk tank — tell us your preferred format and we will quote and classify to it.

Drums

200-180 litre drums

Steel drums, inhibitor-stabilised, for smaller-volume orders and trial quantities.

IBC totes

~1,000 litre totes

Returnable or one-way IBC totes sized for mid-volume converter orders.

Bulk ISO tank / flexi-tank

Large-volume bulk shipment

Pressurised or refrigerated ISO tank bulk shipment for continuous-consumption rubber plants.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for process trials before a commercial order is placed.

Scheduled release

Contracted call-off supply

We hold contracted tonnage and release it against your consumption calendar.

Safety, storage & handling

Extremely flammable & volatile — handle accordingly

Isoprene is extremely flammable, highly volatile, and a suspected human carcinogen, and can form explosive peroxides without adequate inhibitor. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Danger

Classified hazards

  • H224Extremely flammable liquid and vapour.
  • H351Suspected of causing cancer.
  • H315+H319Causes skin and eye irritation.

Maintain inhibitor levels at all times. Inadequately inhibited isoprene can form explosive peroxides in storage; always read the SDS issued with your specific batch and follow site exposure-control procedures.

Storage

Store inhibited material in tightly closed, cooled containers away from heat, sunlight, oxidising agents and oxygen ingress, with adequate ventilation given its low boiling point.

Handling

Use chemical-resistant gloves, eye protection and respiratory protection where vapour control is needed. Avoid inhalation and skin contact; provide forced ventilation and eliminate ignition sources when handling.

Transport

Shipped as UN 1218 (Isoprene, stabilized), an extremely flammable liquid. We confirm and document exact classification for your specific shipment and destination.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Assay, dimer/peroxide content and inhibitor level confirmed against your polymerisation route before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and transport paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How Isoprene is made

Isoprene is recovered industrially mainly as a C5 co-product of ethylene steam cracking, extracted from the pyrolysis gasoline fraction by extractive distillation, in a manner analogous to butadiene recovery from the C4 stream. On-purpose routes, including dehydrogenation of isopentane/isoamylenes, supplement supply where cracker-derived volumes are insufficient.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familyConjugated diene (branched C5)
Functional groupsTwo conjugated carbon-carbon double bonds
ReactivityStereospecific (co)polymerisation; Diels-Alder diene; forms peroxides with oxygen
Related compounds1,3-Butadiene, Isobutylene (related C4/C5 dienes/olefins), Polyisoprene, Butyl Rubber (downstream)
Related building blocks

Explore the wider petrochemical range

Frequently asked

Isoprene, answered

What is Isoprene used for?
Isoprene is used mainly as the monomer for synthetic cis-1,4-polyisoprene rubber, a close match to natural rubber, and as a comonomer for butyl rubber and styrene-isoprene-styrene (SIS) block copolymer adhesives.
How is Isoprene made?
Isoprene is recovered mainly as a C5 co-product of ethylene steam cracking, extracted from pyrolysis gasoline by extractive distillation, with on-purpose dehydrogenation routes supplementing supply.
Is Isoprene hazardous?
Yes. Isoprene is an extremely flammable, highly volatile liquid, classified as a suspected carcinogen (H351), and can form explosive peroxides if inadequately inhibited. It ships as UN 1218. Full regulatory documentation accompanies every consignment.
What grade do you supply?
Polymer-grade isoprene to the purity your polyisoprene, butyl-rubber or SIS process requires. Tell us your end use and we will quote against the correct specification.
What packing do you offer?
Drums, IBC totes, and bulk ISO tank or flexi-tank shipment, sized to rubber and adhesive-plant order volumes.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
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