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Benzene

Benzene · CAS 71-43-2

The foundational aromatic building block — the starting point for styrene/polystyrene, phenol/acetone, nylon intermediates and polyurethane precursors.

Chelora Chemicals supplies benzene to styrene, phenol and nylon-chain producers worldwide, with strict exposure-controlled logistics and full documentation on every consignment.

  • Ethylbenzene & styrene feedstock
  • Cumene & phenol feedstock
  • Cyclohexane / nylon chain
  • Known human carcinogen
  • Highly flammable
  • UN 1114

Product identity

CAS Number
71-43-2
IUPAC name
Benzene
Molecular formula
C₆H₆
Molecular weight
78.11 g/mol
Boiling point
80.1 °C
Melting point
5.5 °C
UN Number
UN 1114
HS Code
2902 20

Note: Benzene is a confirmed human carcinogen and is handled under strict occupational exposure controls throughout its supply chain. Confirm requirements with your regulatory affairs team.

78.11g/mol molecular weight
80.1 °CBoiling point
0.8765g/cm³ density
Slightly solubleWater solubility
Product overview

What Benzene is used for

Benzene is a colourless, highly flammable liquid with a characteristic sweet, aromatic odour, the simplest and highest-volume aromatic hydrocarbon. It is recovered industrially from catalytic reforming of naphtha, pyrolysis gasoline (a steam-cracker co-product), and toluene dealkylation or disproportionation.

Benzene sits at the head of the aromatic petrochemical chain. Its largest use is alkylation with ethylene to ethylbenzene, dehydrogenated to styrene for polystyrene, ABS and SBR. Major derivative routes also include alkylation with propylene to cumene (phenol and acetone), hydrogenation to cyclohexane (the nylon 6,6 and nylon 6 chain via adipic acid and caprolactam), and nitration to nitrobenzene/aniline (MDI for polyurethanes).

Where it sits in the petrochemical value chain

  • Naphtha reforming / Pyrolysis gasoline / Toluene the feedstocks and routes benzene is recovered or produced from.
  • Benzene (this product) the aromatic ring building block for the derivative chains below.
  • Ethylbenzene / Cumene / Cyclohexane / Nitrobenzene major derivative chains built on benzene. See Toluene for a related aromatic feedstock.

Handling character

Benzene is a known human carcinogen and highly flammable, requiring closed-system handling and strict exposure limits. Full hazard detail is in the Safety section below.

Typical commercial specification
ParameterTypical value
AppearanceColourless liquid
Purity99.9% min (nitration/polymer grade)
Sulphur content< 1 ppm (typical polymer grade)
Non-aromatic contentWithin producer specification

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateColourless, highly flammable liquid
Boiling point80.1 °C
Melting point5.5 °C
Density0.8765 g/cm³
Water solubilitySlightly soluble (~1.79 g/L)
Flash point-11 °C (highly flammable)

Physical constants compiled from public reference data for CAS 71-43-2 and rounded for readability. Treat them as orientation, not as a specification.

Applications

Where our customers put Benzene to work

The aromatic ring behind polystyrene, phenolic resins, nylon and polyurethane chains.

Ethylbenzene & styrene

Alkylated with ethylene to ethylbenzene, dehydrogenated to styrene for polystyrene, ABS and SBR.

  • Polymer-grade specification
  • Bulk & drum supply
  • Technical desk review on request

Cumene & phenol/acetone

Alkylated with propylene to cumene, oxidised to phenol and acetone for resins and solvents.

  • Industrial-grade specification
  • Documented batch traceability
  • Contract & spot supply

Cyclohexane / nylon chain

Hydrogenated to cyclohexane, oxidised onward to adipic acid and caprolactam for nylon 6,6 and nylon 6.

  • Full analytical documentation available
  • Retained sample held against the lot

Nitrobenzene & aniline (MDI)

Nitrated to nitrobenzene, reduced to aniline, the feedstock for MDI polyurethane precursors.

  • Documented batch traceability
  • Technical desk review on request

Alkylbenzene & detergents

Alkylated into linear alkylbenzene (LAB), the feedstock for biodegradable detergent surfactants.

  • Research & process-scale quantities
  • Full documentation supplied

Contract & scheduled supply

Styrene, phenol and nylon-chain plants running continuous consumption are supported with scheduled bulk delivery.

  • Annual contracts with scheduled call-off
  • Price held across the contract period
  • Second source held in reserve
Buying from Chelora

How we supply Benzene

Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. Benzene's carcinogen classification makes exposure control, documentation and logistics discipline critical — that shapes how we manage this line.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window, and confirm your jurisdiction's import requirements before booking.

We keep a second qualified source on this line, so a single-plant disruption never becomes your production problem.

  • Purity and sulphur content confirmed before we quote. Consistency matters to downstream styrene, phenol and nylon-chain chemistry.
  • UN 1114 documentation managed end to end. Classification, labelling and carrier compliance confirmed before booking.
  • Scheduled call-off scheduling. We hold contracted tonnage and release it against your consumption calendar.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
  • Export machinery handled in-house. Classification, approved packing, labelling, freight booking and customs paperwork are ours to manage.
  • Nitration and polymer grade both sourced. Matched precisely to your derivative-chain specification.
Packing & logistics

Packed the way your plant receives it

Drum, tote or bulk tank — tell us your preferred format and we will quote and classify to it.

Drums

200-210 litre drums

Steel drums for smaller-volume orders and trial quantities.

IBC totes

~1,000 litre totes

Returnable or one-way IBC totes sized for mid-volume converter orders.

Bulk ISO tank / flexi-tank

Large-volume bulk shipment

ISO tank or flexi-tank bulk shipment for continuous-consumption styrene, phenol and nylon-chain plants.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for process trials before a commercial order is placed.

Scheduled release

Contracted call-off supply

We hold contracted tonnage and release it against your consumption calendar.

Safety, storage & handling

Known human carcinogen — handled under strict controls

Benzene is a confirmed human carcinogen, highly flammable, and genotoxic, requiring closed-system handling and strict occupational exposure limits throughout its supply chain. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Danger

Classified hazards

  • H225Highly flammable liquid and vapour.
  • H350May cause cancer.
  • H340+H372May cause genetic defects; causes damage to organs through prolonged or repeated exposure.

Closed-system handling with strict exposure monitoring. Occupational exposure limits for benzene are very low; always read the SDS issued with your specific batch and follow site exposure-control and monitoring procedures.

Storage

Store in tightly closed containers in a cool, dry, well-ventilated area, segregated from oxidisers and ignition sources, with vapour-recovery or closed-loading systems where required.

Handling

Handle only with engineering controls (closed transfer, local exhaust ventilation) and appropriate PPE; avoid any inhalation, ingestion or skin contact, and monitor workplace exposure continuously.

Transport

Shipped as UN 1114 (Benzene), a highly flammable, carcinogenic liquid. We confirm and document exact classification for your specific shipment and destination.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Purity, sulphur content and non-aromatic impurity levels confirmed against your process requirement before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and transport paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How Benzene is made

Benzene is recovered industrially from three main routes: catalytic reforming of naphtha (extracted from reformate), pyrolysis gasoline (a co-product of ethylene steam cracking, hydrotreated and extracted), and the hydrodealkylation or disproportionation of toluene, which converts toluene to benzene when market demand favours the latter.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familyAromatic hydrocarbon (simple arene)
Functional groupsAromatic ring (delocalised pi system)
ReactivityElectrophilic aromatic substitution (alkylation, nitration); catalytic hydrogenation
Related compoundsToluene, Mixed Xylenes (related arenes), Ethylbenzene, Cumene, Cyclohexane (downstream)
Related aromatics

Explore the wider petrochemical range

Frequently asked

Benzene, answered

What is Benzene used for?
Benzene is used mainly as the feedstock for ethylbenzene/styrene (polystyrene, ABS, SBR), cumene/phenol-acetone, cyclohexane (the nylon chain), and nitrobenzene/aniline (MDI polyurethane precursors).
How is Benzene made?
Benzene is recovered from catalytic reforming of naphtha, from pyrolysis gasoline (a co-product of ethylene steam cracking), and from the hydrodealkylation or disproportionation of toluene.
Is Benzene hazardous?
Yes. Benzene is a confirmed human carcinogen (H350), highly flammable, and may cause genetic defects and organ damage through prolonged exposure. It ships as UN 1114. Full regulatory documentation accompanies every consignment.
What grade do you supply?
Nitration-grade and polymer-grade benzene to the purity your styrene, phenol or nylon-chain process requires. Tell us your end use and we will quote against the correct specification.
What packing do you offer?
Drums, IBC totes, and bulk ISO tank or flexi-tank shipment, sized to styrene, phenol and nylon-chain plant order volumes.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
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