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Dioctyl Phthalate

DOP · CAS 117-81-7

The classic general-purpose plasticiser for flexible PVC — cable, film, flooring and consumer products, now facing regulatory substitution in sensitive uses.

Chelora Chemicals supplies dioctyl phthalate to flexible-PVC compounders worldwide, with clear guidance on where regulatory restrictions apply.

  • Flexible PVC plasticiser
  • Cable, film & flooring compounding
  • Reproductive toxicant / endocrine concern
  • Restricted in children's products & EU
  • Combustible liquid
  • Not DG regulated

Product identity

CAS Number
117-81-7
IUPAC name
Bis(2-ethylhexyl) benzene-1,2-dicarboxylate
Molecular formula
C₂₄H₃₈O₄
Molecular weight
390.56 g/mol
Boiling point
384 °C
Melting point
-50 °C
UN Number
Not regulated
HS Code
2917 32

Note: DOP (DEHP) is restricted or banned in children's products, food-contact and medical-device applications in the EU, US and many other jurisdictions. Confirm your destination's current regulatory status before ordering for a sensitive end use.

390.56g/mol molecular weight
384 °CBoiling point
0.981g/cm³ density
Very lowWater solubility
Product overview

What DOP is used for

Dioctyl Phthalate (DOP), also known as DEHP, is a colourless to pale yellow, oily, high-boiling liquid with very low volatility and very low water solubility. It is produced by the esterification of phthalic anhydride with 2-ethylhexanol, and was historically the highest-volume plasticiser worldwide.

DOP's role is as a general-purpose primary plasticiser for flexible PVC — cable and wire insulation, flexible film and sheet, vinyl flooring, coated fabrics, and general consumer goods — where it is valued for its low cost, good compatibility and efficient flexibilising effect. Regulatory pressure over endocrine-disruption and reproductive-toxicity concerns has driven substitution with non-phthalate or higher-molecular-weight phthalate plasticisers (such as DINP or DOTP) in children's products, food-contact, and medical applications in many jurisdictions.

Where it sits in the petrochemical value chain

  • Phthalic Anhydride the feedstock, esterified with 2-ethylhexanol into DOP. See that page.
  • Dioctyl Phthalate (this product) the general-purpose plasticiser for the flexible-PVC applications below.
  • Polyvinyl Chloride the dominant end use — flexible PVC compounds. See that page.

Handling character

DOP is classified as a suspected reproductive toxicant and is subject to use restrictions in sensitive applications in many jurisdictions. Full hazard detail is in the Safety section below.

Typical commercial specification
ParameterTypical value
AppearanceColourless to pale yellow oily liquid
Assay99.5% min (plasticiser grade)
Colour (APHA)Within producer specification
Acidity< 0.02 mg KOH/g (typical)

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateColourless to pale yellow, oily, high-boiling liquid
Boiling point384 °C
Melting point-50 °C
Density0.981 g/cm³
Water solubilityVery low (practically insoluble)
Flash point210 °C (combustible)

Physical constants compiled from public reference data for CAS 117-81-7 and rounded for readability. Treat them as orientation, not as a specification.

Applications

Where our customers put DOP to work

The workhorse plasticiser behind flexible PVC cable, film, flooring and coated fabrics.

Cable & wire insulation

The dominant plasticiser historically used in flexible PVC cable and wire insulation compounds.

  • Plasticiser-grade specification
  • Bulk & drum supply
  • Technical desk review on request

Flexible film & sheet

Used in calendered flexible PVC film and sheet for industrial and non-sensitive packaging applications.

  • Industrial-grade specification
  • Documented batch traceability
  • Contract & spot supply

Vinyl flooring

Used in flexible PVC flooring compounds for commercial and industrial applications.

  • Full analytical documentation available
  • Retained sample held against the lot

Coated fabrics

Used in flexible PVC-coated fabrics for tarpaulins, upholstery and industrial covers.

  • Documented batch traceability
  • Technical desk review on request

General consumer & industrial goods

Used in a wide range of non-sensitive flexible PVC consumer and industrial products.

  • Research & process-scale quantities
  • Full documentation supplied

Contract & scheduled supply

Flexible-PVC compounders running continuous consumption are supported with scheduled bulk delivery.

  • Annual contracts with scheduled call-off
  • Price held across the contract period
  • Second source held in reserve
Buying from Chelora

How we supply Dioctyl Phthalate

Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. Destination-specific regulatory status for DOP varies by end use — that shapes how we manage this line.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window, and confirm your jurisdiction's import and end-use restrictions before booking.

We keep a second qualified source on this line, so a single-plant disruption never becomes your production problem, and can advise on non-phthalate or DOTP alternatives where your end use is regulated.

  • Destination and end-use regulatory status checked before we quote. DOP is restricted in children's products, food-contact and medical uses in many jurisdictions.
  • Purity and colour grade confirmed before we quote. Consistency matters to downstream PVC compound clarity and performance.
  • Scheduled call-off scheduling. We hold contracted tonnage and release it against your consumption calendar.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
  • Export machinery handled in-house. Classification, approved packing, labelling, freight booking and customs paperwork are ours to manage.
  • Alternative plasticisers advised where needed. We can point you to DOTP or non-phthalate options for regulated end uses.
Packing & logistics

Packed the way your plant receives it

Drum, tote or bulk tank — tell us your preferred format and we will quote and classify to it.

Drums

200-210 litre drums

Steel drums for smaller-volume orders and trial quantities.

IBC totes

~1,000 litre totes

Returnable or one-way IBC totes sized for mid-volume converter orders.

Bulk ISO tank / flexi-tank

Large-volume bulk shipment

ISO tank or flexi-tank bulk shipment for continuous-consumption PVC-compounding plants.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for process trials before a commercial order is placed.

Scheduled release

Contracted call-off supply

We hold contracted tonnage and release it against your consumption calendar.

Safety, storage & handling

Reproductive toxicant / endocrine concern — check your end use

DOP (DEHP) is classified as a suspected reproductive toxicant and is restricted in children's products, food-contact and medical-device applications in many jurisdictions. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Warning

Classified hazards

  • H360FDMay damage fertility; may damage the unborn child.
  • Not acutely toxicLow acute oral and dermal toxicity under typical industrial handling.
  • Regulatory noteSubject to use restrictions (children's products, food-contact, medical devices) in the EU, US and other jurisdictions — confirm before ordering for a sensitive end use.

Check your destination's regulatory status before ordering for a sensitive end use. DOP is widely restricted in children's toys, food-contact articles and medical devices; always read the SDS issued with your specific batch and confirm compliance with our desk.

Storage

Store in tightly closed containers in a cool, dry area away from strong oxidising agents; DOP is a stable, low-volatility liquid under normal storage conditions.

Handling

Standard gloves and eye protection are sufficient for normal industrial handling. Avoid prolonged, repeated skin contact as a matter of good practice given its reproductive-toxicity classification.

Transport

Not classified as dangerous goods for transport. We confirm any destination-specific import or end-use restriction documentation your shipment requires.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Assay, colour grade and acidity confirmed against your process requirement before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and transport/regulatory paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How DOP is made

DOP is produced industrially by the acid-catalysed esterification of phthalic anhydride with 2-ethylhexanol, with excess alcohol used to drive the reaction and water removed continuously. The crude ester is purified by neutralisation, stripping and filtration to the colour and purity grade required for plasticiser use.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familyPhthalate ester (plasticiser)
Functional groupsDiester of an aromatic dicarboxylic anhydride
ReactivityStable under normal conditions; hydrolyses slowly under strong acid/base and heat
Related compoundsPhthalic Anhydride (feedstock), Dioctyl Terephthalate (DOTP, substitute plasticiser)
Frequently asked

Dioctyl Phthalate, answered

What is Dioctyl Phthalate used for?
Dioctyl Phthalate (DOP/DEHP) is used as a general-purpose plasticiser for flexible PVC cable, film, flooring and coated fabrics in non-sensitive industrial and consumer applications.
How is Dioctyl Phthalate made?
DOP is produced by the acid-catalysed esterification of phthalic anhydride with 2-ethylhexanol, followed by neutralisation, stripping and filtration.
Is Dioctyl Phthalate hazardous?
DOP (DEHP) is classified as a suspected reproductive toxicant (may damage fertility and the unborn child) and is restricted or banned in children's products, food-contact articles and medical devices in many jurisdictions, though acute toxicity under normal industrial handling is low.
What grade do you supply?
Plasticiser-grade DOP to the colour and purity your process requires, for non-restricted end uses. Tell us your end use and we will confirm regulatory suitability before quoting.
What packing do you offer?
Drums, IBC totes, and bulk ISO tank or flexi-tank shipment, sized to PVC-compounding plant order volumes.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
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Response timeWithin one business day