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Vinyl Chloride Monomer

VCM · CAS 75-01-4

The sole monomer used to manufacture PVC resin — the polymer behind pipes, cables, profiles, films and a vast share of the world's rigid and flexible plastics.

Chelora Chemicals supplies VCM to PVC and compounding plants worldwide, with pressurised, inhibitor-stabilised handling and full regulatory documentation on every consignment.

  • PVC resin monomer
  • Pipes, cables & profiles
  • Flammable liquefied gas
  • May cause cancer
  • Handle under pressure
  • UN 1086

Product identity

CAS Number
75-01-4
IUPAC name
Chloroethene
Molecular formula
C₂H₃Cl
Molecular weight
62.50 g/mol
Boiling point
-13.4 °C
Melting point
-153.8 °C
UN Number
UN 1086
HS Code
2903 21

Note: VCM is a liquefied gas at ambient temperature and pressure — it ships and is stored under pressure. Confirm exact classification for your shipment with your regulatory affairs team.

62.50g/mol molecular weight
-13.4 °CBoiling point
0.911g/cm³ liquid density
Liquefied gasShipping state
Product overview

What VCM is used for

Vinyl Chloride Monomer (VCM) is a colourless, flammable gas with a mild, sweet odour, handled and shipped as a liquefied gas under its own vapour pressure. It is the two-carbon chloro-olefin formed from ethylene and chlorine, and its entire commercial purpose is as a polymerisation feedstock.

VCM's only significant industrial use is as the monomer for polyvinyl chloride (PVC), produced by free-radical polymerisation (suspension, emulsion or bulk processes) into PVC resin. PVC in turn is compounded into rigid pipe and fittings, window profiles, cable and wire insulation, flexible film and sheet, flooring, and medical tubing. Essentially all VCM produced worldwide is consumed captively or sold directly into PVC manufacture.

Where it sits in the petrochemical value chain

  • Ethylene the feedstock, chlorinated to ethylene dichloride (EDC). See that page.
  • Ethylene Dichloride (EDC) thermally cracked to produce VCM and co-product HCl, which is recycled to make more EDC.
  • Vinyl Chloride Monomer (this product) polymerised to PVC resin — its sole commercial outlet.

Handling character

VCM is extremely flammable and a known human carcinogen, and ships as a pressurised liquefied gas. Full hazard detail is in the Safety section below.

Typical commercial specification
ParameterTypical value
AppearanceColourless liquefied gas
Assay99.9% min (polymer grade)
Acetylene contentWithin producer specification (ppm level)
Stabiliser/inhibitorAs required for the intended polymerisation route

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateLiquefied gas under pressure at ambient temperature
Boiling point-13.4 °C
Melting point-153.8 °C
Density (liquid)0.911 g/cm³
Water solubilitySlightly soluble (~1.1 g/L)
Flash point-78 °C (extremely flammable)

Physical constants compiled from public reference data for CAS 75-01-4 and rounded for readability. Treat them as orientation, not as a specification.

Applications

Where our customers put VCM to work

Effectively one molecule, one destination: PVC resin for the construction, cable and packaging industries.

PVC resin production

Polymerised by suspension, emulsion or bulk processes into PVC homopolymer and copolymer resin.

  • Polymer-grade specification
  • Pressurised bulk & ISO tank supply
  • Technical desk review on request

Pipes & fittings

Rigid PVC pipe, fittings and profiles for water supply, drainage and construction.

  • Documented batch traceability
  • Contract & spot supply

Cable & wire insulation

Flexible PVC compounds for electrical cable jacketing and wire insulation.

  • Full analytical documentation available
  • Retained sample held against the lot

Film, sheet & flooring

Flexible and rigid film, sheet, vinyl flooring and wallcovering applications.

  • Documented batch traceability
  • Technical desk review on request

Medical & profile applications

Medical-grade tubing, window profiles and other specialty PVC compounds.

  • Research & process-scale quantities
  • Full documentation supplied

Contract & scheduled supply

PVC plants running continuous consumption are supported with scheduled bulk delivery.

  • Annual contracts with scheduled call-off
  • Price held across the contract period
  • Second source held in reserve
Buying from Chelora

How we supply Vinyl Chloride Monomer

Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. VCM's carcinogen classification and pressurised handling make producer selection and logistics control critical — that shapes how we manage this line.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window, and confirm your jurisdiction's import and transport requirements before booking.

We keep a second qualified source on this line, so a single-plant disruption never becomes your PVC production problem.

  • Polymer-grade purity confirmed before we quote. Acetylene and inhibitor levels matter to downstream polymerisation performance.
  • UN 1086 documentation managed end to end. Classification, pressurised packaging approval and carrier compliance confirmed before booking.
  • Scheduled call-off scheduling. We hold contracted tonnage and release it against your consumption calendar.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
  • Export machinery handled in-house. Classification, approved pressurised packaging, labelling, freight booking and customs paperwork are ours to manage.
  • Polymer-grade material sourced to your process. Matched precisely to your suspension, emulsion or bulk PVC route.
Packing & logistics

Shipped under pressure, handled with care

ISO tank, pressurised rail car or cylinder — tell us your preferred format and we will quote and classify to it.

Cylinders

Pressurised cylinders

Steel pressure cylinders for small-volume orders and trial quantities.

Bulk ISO tank

Pressurised ISO tank shipment

ISO tank containers rated for liquefied-gas transport, for continuous-consumption PVC plants.

Rail / road tanker

Bulk tanker delivery

Pressurised rail cars or road tankers for large-volume domestic and regional delivery.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with documentation filed before booking.

Small trial packs

Trial / sample quantities

Small pressurised packs dispatched for process trials before a commercial order is placed.

Scheduled release

Contracted call-off supply

We hold contracted tonnage and release it against your consumption calendar.

Safety, storage & handling

May cause cancer — handled under strict controls

VCM is both extremely flammable and a confirmed human carcinogen, and requires pressurised, closed-system handling throughout. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Danger

Classified hazards

  • H220Extremely flammable gas.
  • H280Contains gas under pressure; may explode if heated.
  • H350May cause cancer.

Closed-system handling only. VCM must be handled in sealed, vented systems with continuous gas detection; always read the SDS issued with your specific batch and follow site exposure-control procedures.

Storage

Store in pressurised vessels in a cool, well-ventilated, bunded area away from ignition sources and oxidisers, with continuous leak detection.

Handling

Handle only in closed systems with appropriate gas detection, forced ventilation and PPE; avoid any inhalation or skin contact, and eliminate ignition sources from the handling area.

Transport

Shipped as UN 1086 (Vinyl chloride, stabilized), a flammable, pressurised, carcinogenic gas. We confirm and document exact classification, approved pressure vessels and routing for your specific shipment and destination.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Assay, acetylene content and stabiliser level confirmed against your polymerisation route before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and pressurised-transport paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How VCM is made

VCM is produced industrially from ethylene dichloride (EDC), which is thermally cracked at high temperature to split off hydrogen chloride and form VCM. The EDC itself is made by direct chlorination and oxychlorination of ethylene, with the HCl by-product from cracking recycled back into the oxychlorination step — the balanced chlorine process used by most modern VCM plants.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familyChloro-olefin / vinyl halide
Functional groupsVinyl group with a chlorine substituent
ReactivityFree-radical polymerisation to PVC; requires inhibitor during storage
Related compoundsEthylene, Ethylene Dichloride (feedstock), PVC resin (product)
Frequently asked

Vinyl Chloride Monomer, answered

What is Vinyl Chloride Monomer used for?
Vinyl Chloride Monomer (VCM) is used almost exclusively as the monomer for polyvinyl chloride (PVC) resin, which is polymerised by suspension, emulsion or bulk processes and compounded into pipes, cables, profiles, film, flooring and medical tubing.
How is VCM made?
VCM is produced by thermally cracking ethylene dichloride (EDC), which is itself made by chlorinating and oxychlorinating ethylene. The hydrogen chloride co-product from cracking is recycled back into EDC production in a balanced chlorine process.
Is Vinyl Chloride Monomer hazardous?
Yes. VCM is an extremely flammable gas under pressure and is classified as a known human carcinogen (H350). It must be handled in closed, well-ventilated systems with continuous gas detection. It ships as UN 1086. Full regulatory documentation accompanies every consignment.
What grade do you supply?
Polymer-grade VCM to the purity your suspension, emulsion or bulk PVC process requires. Tell us your end use and we will quote against the correct specification.
What packing do you offer?
Pressurised cylinders, ISO tanks and bulk rail or road tanker shipment, sized to PVC-plant order volumes.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
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