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Borates

Disodium Octaborate DOT · Na₂B₈O₁₃·4H₂O · CAS 12280-03-4

CAS No.12280-03-4

The highly soluble borate behind US wood preservation — sold as DOT, and marketed under names including Polybor and Tim-bor. Far more soluble than borax, which is what makes it work as a diffusible treatment.

Chelora Chemicals is a disodium octaborate supplier and sourcing partner serving wood treaters, insulation manufacturers and agricultural formulators across the United States, with a batch COA and SDS on every consignment.

  • 66–69% B₂O₃
  • WOOD PRESERVATION
  • CELLULOSE INSULATION
  • BORON MICRONUTRIENT
  • POWDER & GRANULAR
  • NOT DG REGULATED
Product Identity Available to order
CAS Number
12280-03-4
EC Number
234-541-0
Chemical name
Disodium octaborate
Molecular formula
Na₂B₈O₁₃·4H₂O
Molecular weight
412.52 g/mol
B₂O₃ content
66.2–69.0%
Forms supplied
Powder · granular
Transport
Not DG regulated
HS Code
2840 20

Note: hydrate naming differs across catalogs. CAS 12280-03-4 is registered as the tetrahydrate, Na₂B₈O₁₃·4H₂O, and that is what Polybor and Tim-bor are. The same CAS is sometimes listed as a pentahydrate. Confirm the hydrate state and B₂O₃ assay against the batch COA rather than the product name.

66–69%B₂O₃ content
412.52g/mol molecular weight
~9.5%Solubility at 20 °C
4H₂OHydrate form
Where it sits

From borate ore to soluble treatment

Disodium octaborate is made by reacting borax with boric acid to lift the boron content and the solubility well above either starting material.

OreTincal · colemanite · ulexite RefiningBorax & boric acid FusionBorax + boric acid blend This productDisodium Octaborate12280-03-4 DownstreamWood treatment · insulation · agriculture

Why it matters: borax dissolves to roughly 5% at room temperature, DOT to around 9.5% — and far higher warm — which is what makes a diffusible wood treatment practical

Product overview

What disodium octaborate is used for

Disodium octaborate is a white, odorless borate powder or granule carrying 66 to 69% B₂O₃ — a higher boron loading than borax, and a much higher solubility. It is made by fusing borax with boric acid, and the result dissolves readily enough to be sprayed, injected or foamed into timber.

That solubility is the whole commercial point. In wood preservation it diffuses into wet or green timber and stays there, controlling fungal decay and wood-boring insects including termites. In cellulose insulation it serves as both flame retardant and pest deterrent. In agriculture it delivers boron as a micronutrient where deficiency limits yield.

Forms and grades we quote against

  • Powder. Dissolves fastest, the standard form for spray and dip treatment solutions and for dry blending.
  • Granular. Dust-free and free-flowing, preferred for bulk handling, bagging lines and broadcast agricultural use.
  • Technical grade, 66–69% B₂O₃. The standard commercial assay for industrial and wood-treatment service.
  • Related inorganics from the same desk: sodium silicofluoride and calcium chloride.

Handling character

Disodium octaborate is a low acute-hazard solid, but borates carry reproductive-toxicity classifications in several jurisdictions. Full detail is in the Safety section below.

Typical commercial specification
ParameterTypical value
AppearanceWhite powder or free-flowing granules
B₂O₃ content66.2–69.0%
Na₂O content≈ 17–19%
Moisture (loss on drying)Per grade specification
Water insolubles0.1% max
Particle sizePer agreed sieve specification

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateWhite odorless crystalline solid
Molecular weight412.52 g/mol
Water solubility≈ 9.5 g/100 mL at 20 °C
Solubility vs boraxRoughly twice that of borax
pH (3% solution)≈ 8.0–8.5
Bulk density≈ 0.8–1.0 g/cm³ by form
Thermal behaviorLoses water of hydration on heating

Physical constants compiled from public reference data for CAS 12280-03-4 and rounded for readability. Solubility rises sharply with temperature. Treat the table as orientation, not as a specification.

Applications

Where US industry puts DOT to work

Wood preservation, insulation, agriculture and industrial fluids — all resting on the same solubility.

Wood preservation & remedial treatment

Diffuses into wet or green timber to control fungal decay and wood-boring insects including termites. The basis of borate wood treatment in the US.

  • Powder for solution make-up
  • Documented batch traceability
  • EPA registration is the formulator’s responsibility

Cellulose insulation

Serves as flame retardant and pest deterrent in blown and batt cellulose insulation, blended dry with the fiber.

  • Granular for dry blending
  • Consistent assay lot to lot
  • Bulk and bagged supply

Boron micronutrient fertilizer

Delivers boron where soil deficiency limits yield, applied as a foliar spray or in blended fertilizer.

Industrial fluids & corrosion inhibition

Buffers and inhibits corrosion in metalworking fluids, antifreeze and water-treatment formulations.

  • Technical grade to your assay
  • Powder or granular
  • Technical desk review on request

Glass, ceramics & frits

A boron source in specialty glass, glaze and frit batches where a soluble borate is preferred to borax.

  • Low insolubles specification
  • Bulk bag supply
  • Retained sample held against the lot

Contract & scheduled supply

Insulation and wood-treatment demand is seasonal, so contracted tonnage and call-off scheduling matter on this line.

  • Annual contracts with scheduled call-off
  • Price held across the contract period
  • Second source held in reserve
United States coverage

Delivered to US plants and ports

We ship disodium octaborate to nominated delivery points across the United States. The regions below are destinations we serve — Chelora Chemicals is a sourcing and supply partner, not a US manufacturer, and does not hold US stock.

Gulf Coast

The largest US chemical cluster, and the usual entry point for bulk consignments.

  • Houston & Galveston, TX
  • New Orleans & Baton Rouge, LA
  • Mobile, AL

Northeast

Container and bulk delivery into the mid-Atlantic and New England manufacturing belt.

  • Newark & Elizabeth, NJ
  • Philadelphia, PA
  • Boston, MA

Southeast

Port-side delivery for the Carolinas, Georgia and Florida processing plants.

  • Savannah, GA
  • Charleston, SC
  • Jacksonville, FL & Norfolk, VA

Midwest & Great Lakes

Inland rail and truck forwarding from the nearest coastal port to the industrial Midwest.

  • Chicago, IL
  • Detroit, MI
  • Cleveland & Columbus, OH

West Coast

Pacific routing for West Coast processors and formulators.

  • Los Angeles & Long Beach, CA
  • Oakland, CA
  • Seattle & Tacoma, WA

Southwest & Mountain

Inland delivery to interior states, forwarded from the Gulf or Pacific gateway.

  • Dallas–Fort Worth, TX
  • Phoenix, AZ
  • Denver, CO

Importing into the United States

Disodium octaborate is a TSCA-regulated chemical substance. Under TSCA section 13 the importer of record, or its authorized agent, must certify to US Customs and Border Protection that each shipment either complies with TSCA or is not subject to it. We confirm the substance's TSCA Inventory status and agree in writing who files that certification before the first consignment moves.

Which party carries that duty follows the Incoterm. On FOB, CFR or CIF terms it is usually the US buyer; on DDP terms it can be the seller or its agent. Safety data sheets and labels are supplied to OSHA's updated Hazard Communication Standard, and the non-hazardous transport documentation is prepared before booking.

  • TSCA IMPORT CERTIFICATION
  • OSHA HAZCOM SDS & LABELS
  • NOT DANGEROUS GOODS
  • US CUSTOMS DOCUMENTATION
US delivery at a glance
ItemHow it works
Delivery pointsAny nominated US plant, terminal or port of discharge
Incoterms quotedFOB · CFR · CIF · DDP
Importer of recordAgreed in writing before the first shipment
TSCA certificationSection 13 positive certification filed at entry
DocumentationBatch COA, SDS, packing list, certificate of origin
Pack formats25 kg bags, bulk bags or bulk

Note: regional coverage describes where we deliver, not where we hold inventory. Lead time depends on producer scheduling and ocean transit to your nominated US port — we confirm both in the quotation.

Buying from Chelora

How we supply disodium octaborate

Chelora Chemicals is a disodium octaborate supplier and sourcing partner, not a manufacturer. On a borate the variables that bite are B₂O₃ assay, particle size and moisture — and the naming confusion between hydrate forms, which we settle before quoting rather than after.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window, and confirm US import requirements before booking.

We keep a second qualified source on this line, so a single-plant disruption never becomes your production problem.

  • B₂O₃ assay confirmed before we quote. The 66–69% band is wide enough to change your dose rate, so we hold the figure you specify.
  • Hydrate state settled in writing. Catalogs disagree on whether this material is the tetrahydrate or pentahydrate — we confirm what the COA actually says before the order is placed.
  • Particle size agreed up front. A dissolution tank and a dry-blending line want different things; powder and granular are not interchangeable.
  • TSCA status and import certification settled first. We confirm Inventory status and agree who files the section 13 certification before the first shipment.
  • Pesticide registration stays with you. Where the end use is a registered wood preservative or insecticide, EPA registration is the formulator’s responsibility, not ours — we supply the raw material and the documentation.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
Packing & logistics

Bagged, bulk-bagged or delivered in bulk

25 kg bags, bulk bags or bulk truck — tell us your handling arrangement and we will quote to it.

Bags

25 kg / 50 lb poly bags

Moisture-barrier bags on stretch-wrapped pallets, the standard unit for treatment plants.

FIBC

1,000 kg bulk bags

Liner-fitted bulk bags for insulation lines and high-volume blending operations.

Bulk

Bulk truck delivery

Bulk delivery to silo for continuous insulation and agricultural blending operations.

Drums & pails

Small sealed units

Sealed units for laboratory, trial and small-batch formulation work.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for solubility and formulation trials before a commercial order.

Safety, storage & handling

Low acute hazard, but check the borate classification

Disodium octaborate has low acute toxicity and is not classed as dangerous goods for transport. The significant question is the reproductive-toxicity classification that several jurisdictions apply to borates as a group. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Danger

Classified hazards

  • H360FDMay damage fertility. May damage the unborn child.
  • H319Causes serious eye irritation.

Classification differs by jurisdiction. The European Union classifies disodium octaborate and several related borates as Repr. 1B, carrying H360FD. Some US safety data sheets classify more narrowly, on eye and skin irritation alone. Because OSHA Hazard Communication follows the classification the supplier assigns, the SDS issued with your batch governs — and your occupational-health program should be built on it rather than on a generic borate profile.

Storage

Store in sealed, moisture-barrier packaging in a dry, covered area off the floor. The material cakes if it takes up moisture, and dissolves readily once wet. Keep away from strong acids and from incompatible oxidizers.

Handling

Handle with dust control and eye protection; the dust irritates eyes. Wear gloves where contact is prolonged. Where the reproductive-toxicity classification applies, follow the exposure controls set out in the batch SDS and your own occupational-health program.

Transport

Disodium octaborate is normally not regulated as dangerous goods for road, rail or sea transport, so no UN number applies to the standard grades. We confirm and document the position for your specific shipment, packaging and destination before booking.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

B₂O₃ assay, hydrate state, particle size, moisture and insolubles confirmed against your requirement before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and TSCA certification data checked by our desk, and pack moisture barrier confirmed, before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How disodium octaborate is made

Disodium octaborate is made by reacting borax with boric acid in a controlled ratio and then drying and sizing the product. Both starting materials come from refined borate ore — tincal, colemanite or ulexite — mined principally in Turkey and in California.

The point of the reaction is solubility. Borax dissolves to roughly 5% at room temperature, which is not enough to carry a useful boron dose into timber in a single application. Disodium octaborate reaches around 9.5% cold and far higher warm, and it carries more B₂O₃ per unit weight. That is why borate wood treatment is built on this material rather than on borax.

Hydrate naming is where catalogs diverge. CAS 12280-03-4 is registered as the tetrahydrate, and that is what the main branded products are. Some suppliers list the same CAS as a pentahydrate. We confirm what the COA states before quoting.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familySoluble sodium borate
Made fromBorax reacted with boric acid
Key propertyRoughly twice the solubility of borax
Boron loading66–69% B₂O₃
Branded equivalentsPolybor, Tim-bor and similar DOT products
DownstreamWood preservation, insulation, boron micronutrient
Frequently asked

Disodium octaborate, answered

What is disodium octaborate used for?
Disodium octaborate is used mainly as a wood preservative, where it diffuses into wet or green timber to control fungal decay and wood-boring insects including termites. It is also used as a flame retardant and pest deterrent in cellulose insulation, as a boron micronutrient fertilizer, and as a buffer and corrosion inhibitor in metalworking fluids and antifreeze.
Is it the tetrahydrate or the pentahydrate?
CAS 12280-03-4 is registered as the tetrahydrate, Na2B8O13.4H2O, and that is what the main branded products such as Polybor and Tim-bor are. Some catalogs list the same CAS number as a pentahydrate, which is why the two names circulate for what is commercially the same material. The practical answer is to confirm the hydrate state and the B2O3 assay against the batch certificate of analysis rather than relying on the product name.
Why use disodium octaborate instead of borax?
Solubility. Borax dissolves to roughly 5% at room temperature, which is not enough to carry a useful boron dose into timber in one application. Disodium octaborate reaches around 9.5% cold and far higher warm, and carries more B2O3 per unit weight at 66 to 69%. That difference is what makes diffusible borate wood treatment practical.
What is the difference between powder and granular?
They are the same material at different particle sizes. Powder dissolves fastest and suits spray and dip solution make-up and dry blending. Granular is dust-free and free-flowing, which suits bulk handling, bagging lines and broadcast agricultural application. A dissolution tank and a dry-blending line want different things, so the form is part of the order.
Is disodium octaborate hazardous?
Its acute toxicity is low and it is not classed as dangerous goods for transport. The significant question is classification: the European Union classifies disodium octaborate and related borates as reproductive toxicants carrying H360FD, while some US safety data sheets classify more narrowly on eye irritation. OSHA Hazard Communication follows the classification the supplier assigns, so the SDS issued with your batch governs.
Do you supply EPA-registered wood preservative?
No. We supply the raw material with full documentation. Where the end use is a registered wood preservative or insecticide, the EPA product registration sits with the formulator or the registrant, not with the raw material supplier. Confirm your registration position with your regulatory team before formulating for sale.
What B2O3 content do you supply?
The standard technical grade runs 66.2 to 69.0% B2O3. That band is wide enough to change your dose rate, so we hold the figure you specify rather than quoting the range. Sodium oxide content, moisture, insolubles and particle size are agreed alongside it.
What packing do you offer?
25 kg and 50 lb moisture-barrier poly bags on stretch-wrapped pallets, 1,000 kg bulk bags for insulation and blending lines, bulk truck delivery to silo, and sealed pails and drums for small quantities. Trial quantities are dispatched for solubility and formulation trials before a commercial order.
Do you supply disodium octaborate in the United States?
Yes. We deliver to plants, treatment facilities and ports across the United States, including the Gulf Coast, Northeast, Southeast, Midwest, West Coast and Southwest. Chelora Chemicals is a sourcing and supply partner rather than a US manufacturer, so material is placed with a qualified producer and shipped to your nominated US delivery point on the Incoterm your purchasing team works to.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
Ready to order?

Get a quote on disodium octaborate

Send us your required B₂O₃ assay, form, particle size, pack size and US delivery point. We will come back with a firm quote, lead time and full documentation — and will confirm the hydrate state on the COA before you commit.

Emailsource@cheloragroup.com
Phone / WhatsApp+91 98191 11179
Delivering toAll United States regions
Response timeWithin one business day