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Maleic Anhydride

Maleic Anhydride · CAS 108-31-6

The key feedstock for unsaturated polyester resins — the reactive anhydride behind fibreglass composites, coatings and lubricant additives.

Chelora Chemicals supplies maleic anhydride in briquette, flake and molten form to UPR and specialty-chemical producers worldwide.

  • Unsaturated polyester resin feedstock
  • Fumaric acid & copolymer uses
  • Lubricant additive chain
  • Corrosive & respiratory irritant
  • Molten or solid shipment
  • UN 2215

Product identity

CAS Number
108-31-6
IUPAC name
Furan-2,5-dione
Molecular formula
C₄H₂O₃
Molecular weight
98.06 g/mol
Boiling point
202 °C
Melting point
52.8 °C
UN Number
UN 2215
HS Code
2917 14

Note: Maleic anhydride is often handled molten in bulk logistics given its moderate melting point. Confirm requirements with your regulatory affairs team.

98.06g/mol molecular weight
52.8 °CMelting point
202 °CBoiling point
1.48g/cm³ density
Product overview

What Maleic Anhydride is used for

Maleic Anhydride (MAN) is a white, crystalline solid with a sharp, acrid odour, melting just above room temperature and commonly handled molten in bulk. It is produced industrially by the catalytic vapour-phase oxidation of n-butane (the dominant modern route) or, in older plants, from benzene.

Maleic anhydride's largest use by far is as the feedstock for unsaturated polyester resins (UPR), reacted with propylene or ethylene glycol and crosslinked with styrene for fibreglass-reinforced composites, gel coats and cultured marble. It is also hydrogenated to 1,4-butanediol and tetrahydrofuran, converted to fumaric acid for food and resin use, and copolymerised into lubricant additives and agricultural adjuvants.

Where it sits in the petrochemical value chain

  • n-Butane the feedstock, catalytically oxidised into maleic anhydride (sourced from LPG/NGL fractionation, not separately listed on this site).
  • Maleic Anhydride (this product) the reactive anhydride for the UPR and derivative chains below.
  • Unsaturated Polyester Resin the dominant downstream use, crosslinked with styrene and MPG/MEG. See Styrene Monomer.

Handling character

Maleic anhydride is corrosive to skin and eyes and a strong respiratory irritant/sensitiser, requiring careful handling whether solid or molten. Full hazard detail is in the Safety section below.

Typical commercial specification
ParameterTypical value
AppearanceWhite briquettes, flakes, or molten liquid
Assay99.5% min (UPR grade)
Colour (molten, APHA)Within producer specification
Free maleic acid< 0.1% (typical)

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateCrystalline solid, often handled molten above 53 °C
Melting point52.8 °C
Boiling point202 °C
Density1.48 g/cm³
Water solubilityReacts with water (hydrolyses to maleic acid)
Flash point102 °C (combustible)

Physical constants compiled from public reference data for CAS 108-31-6 and rounded for readability. Treat them as orientation, not as a specification.

Applications

Where our customers put Maleic Anhydride to work

The reactive anhydride behind fibreglass composites, coatings and lubricant additives.

Unsaturated polyester resins

Reacted with glycols and crosslinked with styrene for fibreglass-reinforced composites and gel coats.

  • UPR-grade specification
  • Molten & solid bulk supply
  • Technical desk review on request

1,4-Butanediol / THF chain

Hydrogenated into 1,4-butanediol and tetrahydrofuran for spandex and engineering-plastic chains.

  • Industrial-grade specification
  • Documented batch traceability
  • Contract & spot supply

Fumaric acid

Isomerised to fumaric acid for food acidulant and resin applications.

  • Full analytical documentation available
  • Retained sample held against the lot

Lubricant additives

Copolymerised into polyisobutylene-maleic anhydride dispersants and lubricant additives.

  • Documented batch traceability
  • Technical desk review on request

Agricultural adjuvants

Copolymerised into agricultural adjuvants and surfactant intermediates.

  • Research & process-scale quantities
  • Full documentation supplied

Contract & scheduled supply

UPR and specialty-chemical plants running continuous consumption are supported with scheduled bulk delivery.

  • Annual contracts with scheduled call-off
  • Price held across the contract period
  • Second source held in reserve
Buying from Chelora

How we supply Maleic Anhydride

Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. Colour grade and free-acid content are critical to UPR clarity and cure performance — that shapes how we manage this line.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window, and confirm your jurisdiction's import requirements before booking.

We keep a second qualified source on this line, so a single-plant disruption never becomes your production problem.

  • Colour grade and free-acid content confirmed before we quote. Consistency matters to downstream UPR clarity and cure performance.
  • UN 2215 documentation managed end to end. Classification, labelling and carrier compliance confirmed before booking, whether solid or molten.
  • Scheduled call-off scheduling. We hold contracted tonnage and release it against your consumption calendar.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
  • Export machinery handled in-house. Classification, approved packing, labelling, freight booking and customs paperwork are ours to manage.
  • UPR-grade and technical-grade both sourced. Matched precisely to your end-use specification.
Packing & logistics

Solid or molten, packed to your process

Briquette/flake bags, totes or molten bulk tank — tell us your preferred format and we will quote and arrange it.

Briquette/flake bags

25 kg bags

Multi-wall bags of briquetted or flaked solid for smaller-volume orders and trial quantities.

FIBC / jumbo bags

~1,000 kg bulk bags

Flexible intermediate bulk containers sized for mid-volume converter orders.

Molten bulk ISO tank

Temperature-controlled bulk shipment

Heated ISO tank bulk shipment for continuous-consumption UPR plants.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for process trials before a commercial order is placed.

Scheduled release

Contracted call-off supply

We hold contracted tonnage and release it against your consumption calendar.

Safety, storage & handling

Corrosive & sensitising — handle accordingly

Maleic anhydride is corrosive to skin and eyes, a strong respiratory irritant, and a known respiratory and skin sensitiser. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Danger

Classified hazards

  • H314Causes severe skin burns and eye damage.
  • H335May cause respiratory irritation.
  • H317+H334May cause an allergic skin reaction; may cause allergy or asthma symptoms or breathing difficulties if inhaled.

Control dust and avoid any skin/eye contact. Maleic anhydride reacts with moisture (including sweat) to form corrosive maleic acid on contact; always read the SDS issued with your specific batch.

Storage

Store solid product in tightly sealed, moisture-proof containers; store molten product in heated, corrosion-resistant, nitrogen-padded tanks away from moisture and oxidising agents.

Handling

Use chemical-resistant gloves, face shield, and respiratory protection where dust or fumes may be generated. Avoid any skin or eye contact and inhalation of dust or vapour; ensure good ventilation during molten transfer.

Transport

Shipped as UN 2215 (Maleic anhydride), a corrosive solid or molten substance. We confirm and document exact classification for your specific shipment and destination.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Assay, colour grade and free-acid content confirmed against your process requirement before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and transport paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How Maleic Anhydride is made

Maleic anhydride is produced industrially by the catalytic vapour-phase oxidation of n-butane over vanadium-phosphorus-oxide catalysts, the dominant modern route, having largely displaced the older benzene-oxidation process on cost and environmental grounds. The crude product is purified by distillation and crystallised or kept molten for bulk handling.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familyCyclic anhydride (unsaturated dicarboxylic)
Functional groupsCyclic anhydride with an internal carbon-carbon double bond
ReactivityEsterification with glycols; Diels-Alder and ene reactions; hydrolysis to maleic acid
Related compoundsPhthalic Anhydride (related anhydride), Styrene Monomer, Mono Propylene Glycol (UPR co-reactants)
Frequently asked

Maleic Anhydride, answered

What is Maleic Anhydride used for?
Maleic Anhydride (MAN) is used mainly as the feedstock for unsaturated polyester resins (UPR), with further use in 1,4-butanediol/THF production, fumaric acid, lubricant additives and agricultural adjuvants.
How is Maleic Anhydride made?
Maleic anhydride is produced by the catalytic vapour-phase oxidation of n-butane over vanadium-phosphorus-oxide catalysts, the dominant modern production route.
Is Maleic Anhydride hazardous?
Yes. Maleic anhydride is corrosive to skin and eyes, causes respiratory irritation, and is a known skin and respiratory sensitiser. It ships as UN 2215. Full regulatory documentation accompanies every consignment.
What grade do you supply?
UPR-grade maleic anhydride in briquette, flake or molten form to the colour and purity your process requires. Tell us your end use and we will quote against the correct specification.
What packing do you offer?
25 kg briquette/flake bags, FIBC bulk bags, and molten bulk ISO tank shipment, sized to UPR-plant order volumes.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
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Response timeWithin one business day