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Polybutadiene Rubber

PBR · CAS 9003-17-2

A high-resilience elastomer — blended into tyre tread for low rolling resistance, moulded into golf ball cores, and used as an impact modifier.

Chelora Chemicals supplies high-cis polybutadiene rubber in bale form to tyre, sporting-goods and polymer-modification producers worldwide.

  • Tyre tread/sidewall blend component
  • Golf ball core rubber
  • ABS/HIPS impact modifier feedstock
  • Non-hazardous solid rubber
  • Combustible solid
  • Not DG regulated

Product identity

CAS Number
9003-17-2
Polymer type
Homopolymer (1,3-butadiene)
Cis-1,4 content
~96% (high-cis grade); varies by catalyst system
Density
0.91 g/cm³
Glass transition (Tg)
~-100 to -95 °C
Form supplied
Baled solid rubber
UN Number
Not regulated
HS Code
4002 20

Note: High-cis and low-cis grades differ significantly in resilience and processing behaviour; confirm your target grade with our technical desk.

0.91g/cm³ density
~96%Typical cis-1,4 content
High resilienceKey property
BaledSupply form
Product overview

What PBR is used for

Polybutadiene Rubber (BR) is a high-resilience elastomeric homopolymer of 1,3-butadiene, produced mainly by solution polymerisation using Ziegler-Natta, nickel, cobalt or neodymium catalyst systems that give high cis-1,4 microstructure content, the configuration responsible for BR's hallmark low heat build-up and high rebound resilience.

BR's largest use is blended with natural rubber or SBR in tyre tread and sidewall compounds, where its low rolling resistance and good low-temperature flexibility improve fuel economy and wet/winter traction. It is also moulded into golf ball cores for its high resilience and energy return, and used as an impact modifier grafted into ABS and high-impact polystyrene.

Where it sits in the petrochemical value chain

  • 1,3-Butadiene the sole monomer, polymerised into polybutadiene rubber. See that page.
  • Polybutadiene Rubber (this product) the resilient elastomer for tyre blends, golf balls and impact-modifier uses.
  • Styrene-Butadiene Rubber often blended with BR in tyre compounds. See that page.

Handling character

BR bale rubber is not classified as hazardous under normal handling, though it is a combustible solid and should be stored away from ignition sources. Full handling detail is in the Safety section below.

Typical commercial specification
ParameterTypical value
AppearanceLight tan to amber baled solid rubber
Cis-1,4 content~96% (high-cis); other grades available
Mooney viscosity (ML 1+4, 100°C)Grade dependent, confirmed at order
Bale weight~33-35 kg (typical)

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateSolid, baled elastomer
Glass transition (Tg)-100 to -95 °C
Density0.91 g/cm³
ResilienceHigh — a key reason for tyre and golf-ball use
Low-temperature flexibilityExcellent
FlammabilityCombustible solid

Physical constants compiled from public reference data for CAS 9003-17-2 and rounded for readability. Treat them as orientation, not as a specification.

Applications

Where our customers put PBR to work

The resilient rubber behind low-rolling-resistance tyres, golf balls and impact-modified plastics.

Tyre tread & sidewall blends

Blended with natural rubber or SBR to lower rolling resistance and improve low-temperature flexibility.

  • Tyre-grade specification
  • Bale & container-load supply
  • Technical desk review on request

Golf ball cores

Moulded into high-resilience cores for two- and three-piece golf balls.

  • Sporting-goods grade specification
  • Documented batch traceability
  • Contract & spot supply

ABS / HIPS impact modifier

Grafted into ABS and high-impact polystyrene to improve impact resistance.

  • Full analytical documentation available
  • Retained sample held against the lot

Mechanical rubber goods

Compounded into belts, hoses and other mechanical rubber goods requiring resilience.

  • Documented batch traceability
  • Technical desk review on request

Polymer modification blends

Used as a flexibilising and impact-enhancing blend component in various thermoplastic compounds.

  • Research & process-scale quantities
  • Full documentation supplied

Contract & scheduled supply

Tyre and polymer-modification plants running continuous consumption are supported with scheduled bulk delivery.

  • Annual contracts with scheduled call-off
  • Price held across the contract period
  • Second source held in reserve
Buying from Chelora

How we supply Polybutadiene Rubber

Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. Cis-1,4 content and Mooney viscosity consistency are critical to tyre-compound and golf-ball performance — that shapes how we manage this line.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window, and confirm your jurisdiction's import requirements before booking.

We keep a second qualified source on this line, so a single-plant disruption never becomes your production problem.

  • Cis-1,4 content and Mooney viscosity confirmed before we quote. Consistency matters to downstream tyre, golf-ball and impact-modifier performance.
  • High-cis and other grades both sourced. Matched precisely to your tyre-blend or impact-modifier specification.
  • Scheduled call-off scheduling. We hold contracted tonnage and release it against your consumption calendar.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
  • Export machinery handled in-house. Classification, approved packing, labelling, freight booking and customs paperwork are ours to manage.
  • Container-load and bulk bale logistics managed. Palletised bale shipments arranged to your receiving dock requirements.
Packing & logistics

Packed the way your plant receives it

Palletised bales or container-load shipment — tell us your preferred format and we will quote and arrange it.

Film-wrapped bales

~33-35 kg bales

Film-wrapped bales, palletised, for smaller-volume orders and trial quantities.

Palletised bale units

~1,000-1,200 kg pallets

Shrink-wrapped pallets of bales sized for mid-volume converter orders.

Container-load bulk

Full container loads

Full container-load bale shipment for continuous-consumption tyre and polymer-modification plants.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for process trials before a commercial order is placed.

Scheduled release

Contracted call-off supply

We hold contracted tonnage and release it against your consumption calendar.

Safety, storage & handling

Non-hazardous solid rubber — handle sensibly

Baled polybutadiene rubber is not classified as hazardous under GHS for normal handling, but it is combustible and processing fumes should be managed with adequate ventilation. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Not a GHS-classified hazard (bale form)

Classified hazards

  • Not classifiedBaled rubber is not classified as hazardous under GHS.
  • Processing noteProcessing fumes (compounding, curing) should be managed with adequate ventilation per equipment guidance.

Store away from ignition sources. Baled rubber is combustible; avoid prolonged exposure to direct sunlight and ozone, which can degrade physical properties over time. Always read the SDS issued with your specific batch.

Storage

Store baled rubber in a cool, dry, covered area away from direct sunlight, ozone sources and ignition sources to preserve physical properties.

Handling

Standard PPE is sufficient for normal bale handling. Ensure adequate ventilation during compounding and curing operations where fumes may be generated.

Transport

Not classified as dangerous goods for transport in bale form. We confirm any destination-specific import documentation your shipment requires.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Cis-1,4 content, Mooney viscosity and grade confirmed against your process requirement before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and transport paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How PBR is made

Polybutadiene rubber is produced industrially by solution polymerisation of 1,3-butadiene using Ziegler-Natta (titanium, cobalt, nickel) or neodymium-based catalyst systems, each giving different cis-1,4/trans-1,4/vinyl microstructure ratios; high-cis catalyst systems are preferred for maximum resilience and minimum heat build-up in tyre and golf-ball applications. The polymer is coagulated, dried and baled for shipment.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Polymer familyDiene elastomer (homopolymer)
Production routeSolution polymerisation with Ziegler-Natta, nickel, cobalt or neodymium catalysts
Key propertiesHigh resilience, low heat build-up, excellent low-temperature flexibility
Related compounds1,3-Butadiene (monomer), Styrene-Butadiene Rubber (related elastomer)
Frequently asked

Polybutadiene Rubber, answered

What is Polybutadiene Rubber used for?
Polybutadiene Rubber (BR) is used mainly blended into tyre tread and sidewall compounds for low rolling resistance, moulded into golf ball cores for high resilience, and as an impact modifier grafted into ABS and high-impact polystyrene.
How is Polybutadiene Rubber made?
BR is produced by solution polymerisation of 1,3-butadiene using Ziegler-Natta, nickel, cobalt or neodymium catalyst systems, with high-cis catalyst systems preferred for maximum resilience, then coagulated, dried and baled.
Is Polybutadiene Rubber hazardous?
No. Baled BR rubber is not classified as hazardous under GHS for normal handling. It is combustible and should be stored away from ignition sources, and processing fumes should be managed with adequate ventilation.
What grade do you supply?
High-cis polybutadiene rubber at the cis-1,4 content and Mooney viscosity your tyre, golf-ball or impact-modifier process requires. Tell us your end use and we will quote against the correct specification.
What packing do you offer?
Film-wrapped bales, shrink-wrapped pallets, and full container-load bulk shipment, sized to tyre and polymer-modification plant order volumes.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
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Response timeWithin one business day