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Vinyl Acetate Monomer

VAM · CAS 108-05-4

The precursor monomer to PVAc, EVA and PVOH — the starting point for adhesives, coatings, films, foams and personal-care polymers worldwide.

Chelora Chemicals supplies VAM to polymer manufacturers worldwide, with full documentation, inhibitor-stabilised formulation and consistent purity on every consignment.

  • PVAc precursor
  • EVA copolymer precursor
  • PVOH precursor
  • Extremely flammable liquid
  • Suspected carcinogen
  • UN 1301

Product identity

CAS Number
108-05-4
IUPAC name
Ethenyl acetate
Molecular formula
C₄H₆O₂
Molecular weight
86.09 g/mol
Boiling point
72.7 °C
Melting point
-93.5 °C
UN Number
UN 1301
HS Code
2915 32

Note: VAM requires inhibitor-stabilised formulation to prevent premature polymerisation during storage and transport; we confirm the exact classification for your specific shipment before booking.

86.09g/mol molecular weight
72.7 °CBoiling point
0.934g/cm³ density
3major polymer families (PVAc/EVA/PVOH)
Product overview

What Vinyl Acetate Monomer is used for

Vinyl Acetate Monomer (VAM) is a colourless, flammable liquid with a characteristic sharp, fruity odour, the ester of acetic acid and acetaldehyde (vinyl alcohol). It is shipped inhibitor-stabilised to prevent premature polymerisation during storage and transport.

VAM is the foundational monomer for a distinct family of vinyl polymer chemistry. Its largest downstream products are polyvinyl acetate (PVAc), used in adhesives, paints and coatings; ethylene-vinyl acetate (EVA) copolymer, used in foams, films, hot-melt adhesives and footwear; and polyvinyl alcohol (PVOH), used in textile sizing, packaging film and paper coatings. VAM is also copolymerised into vinyl-acetate/acrylic-acid (VA/AA) copolymers and PVCA, and into VP/VA copolymers used in hair gels and personal-care formulations, and finds use in organic synthesis via transacetylation and Diels-Alder reactions.

A distinct chemistry family

  • Not part of the polyester chain. VAM shares no monomers or production routes with the ethylene-glycol/terephthalate chemistry (MEG, PTA, DMT, PET) covered elsewhere in our range.
  • Not part of the polyamide chain. It is unrelated to the caprolactam/adipic-acid chemistry behind Nylon 6 and Nylon 6,6.
  • Vinyl polymer chemistry. VAM stands as its own feedstock family, supplying PVAc, EVA and PVOH production.

Handling character

VAM carries a GHS Danger signal word, as an extremely flammable liquid and suspected carcinogen. Full hazard detail is in the Safety section below.

Typical commercial specification
ParameterTypical value
AppearanceClear, colourless liquid
Assay99.9% min (polymer grade)
Inhibitor contentWithin producer specification
Acidity (as acetic acid)Within producer specification

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateClear, colourless, flammable liquid
Boiling point72.7 °C
Melting point-93.5 °C
Density0.934 g/cm³
Flash point~-8 °C (extremely flammable)

Physical constants compiled from public reference data for CAS 108-05-4 and rounded for readability. Treat them as orientation, not as a specification.

Applications

Where our customers put this monomer to work

One monomer, three major downstream polymer families.

Polyvinyl acetate (PVAc)

Polymerised into PVAc for wood/paper adhesives, paints and coatings.

  • Polymer-grade specification
  • Drum & bulk supply
  • Technical desk review on request

Ethylene-vinyl acetate (EVA)

Copolymerised with ethylene to form EVA for foams, film and hot-melt adhesives.

  • Consistent purity specification
  • Documented batch traceability

Polyvinyl alcohol (PVOH)

Hydrolysed from PVAc precursor to form PVOH for textile sizing and packaging film.

  • Contract & spot supply
  • Full analytical documentation available

VA/AA & PVCA copolymers

Copolymerised with acrylic acid or vinyl chloride for specialty copolymer applications.

  • Packs sized to customer volumes
  • Retained sample held against the lot

VP/VA copolymers for personal care

Used in VP/VA copolymers found in hair gels and personal-care formulations.

  • Research & process-scale quantities
  • Full documentation supplied

Contract & scheduled supply

Polymer plants running continuous consumption are supported with scheduled bulk delivery.

  • Annual contracts with scheduled call-off
  • Second source held in reserve
Buying from Chelora

How we supply Vinyl Acetate Monomer

Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. Inhibitor stabilisation and purity are critical given VAM's flammability and polymerisation tendency — that shapes how we manage this line.

We place your order with whichever qualified producer best matches your required grade, your price point and your delivery window, and confirm your jurisdiction's import requirements before booking.

We keep a second qualified source on this line, so a single-plant disruption never becomes your production problem.

  • Inhibitor-stabilised formulation confirmed before we quote. Consistency matters to safe storage and transport.
  • UN 1301 documentation managed end to end. Classification, labelling and carrier compliance confirmed before booking.
  • Scheduled call-off scheduling. We hold contracted tonnage and release it against your consumption calendar.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
  • Export machinery handled in-house. Classification, approved packing, labelling, freight booking and customs paperwork are ours to manage.
  • Polymer-grade sourced to your specification. Matched precisely to your PVAc, EVA or PVOH process.
Packing & logistics

Packed the way your plant receives it

Drum or bulk tank, always inhibitor-stabilised — tell us your preferred format and we will quote and classify to it.

Drums

200 litre drums

Steel drums for smaller-volume orders and trial quantities, inhibitor-stabilised.

Bulk ISO tank / flexi-tank

Large-volume bulk shipment

ISO tank or flexi-tank bulk shipment for continuous-consumption polymer plants.

Hazmat-compliant handling

UN 1301 classification

Shipped and labelled per UN 1301 flammable-liquid dangerous-goods regulations throughout.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for process trials before a commercial order is placed.

Scheduled release

Contracted call-off supply

We hold contracted tonnage and release it against your consumption calendar.

Safety, storage & handling

Extremely flammable liquid — suspected carcinogen

VAM demands strict control of ignition sources and inhalation exposure. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Danger

Classified hazards

  • H225Highly flammable liquid and vapour.
  • H332Harmful if inhaled.
  • H335May cause respiratory irritation.
  • H351Suspected of causing cancer.

Strict ignition-source control required. Keep away from heat, sparks, open flame and all other ignition sources; always read the SDS issued with your specific batch and store accordingly.

Storage

Store in tightly closed, inhibitor-stabilised containers in a cool, well-ventilated area, away from heat, sparks and all ignition sources, and segregated from oxidisers and polymerisation initiators.

Handling

Use standard PPE (gloves, eye protection, respiratory protection where ventilation is limited). Bond and ground equipment during transfer to control static discharge; monitor inhibitor levels during extended storage.

Transport

Shipped as UN 1301 (flammable liquid, Class 3) with inhibitor-stabilised formulation maintained throughout. We confirm and document the exact classification for your specific shipment and destination.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Assay, inhibitor content and acidity confirmed against your process requirement before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS and transport paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

Where VAM fits in polymer chemistry

VAM is the ester of acetic acid and vinyl alcohol, carrying a reactive vinyl (C=C) group that enables free-radical polymerisation. Polymerised alone, it forms polyvinyl acetate (PVAc); copolymerised with ethylene, it forms EVA; and PVAc can be further hydrolysed to form polyvinyl alcohol (PVOH). Its vinyl group also copolymerises readily with acrylic acid, vinyl chloride and other vinyl monomers.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familyVinyl ester
Functional groupVinyl (C=C) ester group
ReactivityFree-radical homopolymerisation (PVAc) and copolymerisation (EVA, VA/AA, VP/VA)
Related polymersPolyvinyl Acetate, EVA copolymer, Polyvinyl Alcohol (PVOH)
Explore our range

Browse the full product catalogue

VAM sits in its own vinyl-polymer chemistry family; for the polyester and polyamide intermediates on this site, see the categories below.

Frequently asked

Vinyl Acetate Monomer, answered

What is Vinyl Acetate Monomer used for?
Vinyl Acetate Monomer (VAM) is the precursor to polyvinyl acetate (PVAc), used in adhesives, paints and coatings; to ethylene-vinyl acetate (EVA) copolymer, used in foams, films and hot-melt adhesives; and to polyvinyl alcohol (PVOH), used in textile sizing, packaging film and paper coatings. It is also copolymerised into vinyl-acetate/acrylic-acid (VA/AA) copolymers and PVCA, and into VP/VA copolymers used in hair gels and personal-care formulations.
Is Vinyl Acetate Monomer part of the polyester/polyamide chemistry on this site?
No. VAM belongs to a distinct vinyl-polymer chemistry family, separate from the polyester (PET) and polyamide (Nylon) chemistry of most other intermediates in our Petrochemical Intermediates range. It does not share monomers or production routes with the ethylene-glycol, terephthalate or caprolactam/adipic-acid chemistry covered elsewhere on this site.
Is Vinyl Acetate Monomer hazardous?
Yes. VAM carries a GHS Danger signal word, classified as an extremely flammable liquid and vapour, harmful if inhaled, may cause respiratory irritation, and suspected of causing cancer. It ships as UN 1301. Full regulatory documentation accompanies every consignment.
What grade do you supply?
Polymer-grade VAM to the purity your PVAc, EVA, PVOH or copolymer process requires. Tell us your end use and we will quote against the correct specification.
What packing do you offer?
Drums and bulk ISO tank or flexi-tank shipment, with inhibitor-stabilised formulation maintained throughout transport and storage.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer fits your specification and timeline, and hold a second source in reserve.
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