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Crop Protection & Copper Chemicals

Bordeaux Mixture 20% WDG (Blue) Blue shade · 20% Cu as metal · WDG

CAS No.8011-63-0

The hardest of the Bordeaux grades to hold on shade — because granulation changes how the color reads, and attrition changes it again in transit.

Chelora Chemicals is a blue Bordeaux 20% WDG supplier and sourcing partner serving registrants and distributors across the United States, with shade, dustiness and attrition all agreed before dispatch.

  • SHADE-MATCHED GRANULE
  • 20% Cu AS METAL
  • DUST-FREE
  • ATTRITION SPECIFIED
  • FRAC M1
  • UN 3077 CLASS 9
Product Identity Available to order
CAS Number
8011-63-0
Formulation type
Water dispersible granule — WDG
Copper as Cu
20% w/w
Composition
Copper sulfate + hydrated lime
Shade
Blue, matched to reference sample
FRAC group
M1 — multi-site contact
Appearance
Blue to blue-green granule
Transport
UN 3077 · Class 9 · PG III
HS Code
3808 92

Note: shade is harder to hold in a granule than in a powder. Granulation changes how color reads: the granule surface, the size distribution and the binder all affect what the eye sees, even at identical composition. Worse, attrition works against the shade too — granules that crumble back to powder in transit present a finer surface and read differently from the lot you approved. On this grade, shade and attrition resistance have to be specified together.

20%Copper as metal
WDGGranule — not powder
M1FRAC group
3077UN number
Where it sits

Shade, through granulation

Every step from blend to granule moves the appearance. Holding a shade through all of them is the specification.

BlendCopper sulfate + hydrated lime Shade setGrade · lime ratio · fineness GranulationBinder, agglomeration, size distribution This productBordeaux Mixture 20% WDG (Blue)8011-63-0 Risk in transitAttrition — finer surface reads differently

Why it matters: attrition is both a dust problem and a shade problem on this grade — the same parameter protects you from each

Product overview

Why shade is harder in a granule

Blue Bordeaux 20% WDG carries the same chemistry as every other Bordeaux grade — copper sulfate and hydrated lime at 20% copper expressed as metal, FRAC M1 multi-site contact — in a dust-free granule with the shade written into the specification.

Combining those two requirements is genuinely harder than either alone. In a powder, shade follows composition and fineness. In a granule, it also follows the granule surface, the size distribution and the binder, so two lots of identical composition can read differently. And attrition makes it worse: granules that crumble back toward powder in transit present a finer, more light-scattering surface than the lot you signed off. That is why attrition resistance is not only a dust specification on this grade — it is a shade specification too.

What has to be specified together here

  • Shade, against a retained reference sample. There is no published numeric standard for Bordeaux color.
  • Attrition resistance. Protects both the dust-free claim and the shade you approved.
  • Size distribution. Changes perceived color independently of composition.
  • The powder equivalent: blue Bordeaux technical.

Handling character

Bordeaux is a Class 9 dangerous good, corrosive to equipment and phytotoxic on new growth. Full detail is in the Safety section below.

Typical shade-specified WDG specification
ParameterTypical value
AppearanceBlue to blue-green free-flowing granule
ShadeMatched to retained reference sample
Copper as Cu20% w/w ± tolerance
Dispersibility & suspensibilityPer agreed specification
Dustiness & attrition resistancePer agreed specification
Size distribution & flowabilityPer agreed specification

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateBlue to blue-green granule
NatureMixture, not a single compound
Water behaviorGranules disintegrate and disperse
Mode of actionMulti-site contact; FRAC M1
Tank stabilityUse the same day once mixed
RainfastnessLonger lasting than fixed coppers
EquipmentHighly corrosive; rinse thoroughly

Characteristics compiled from public agricultural extension guidance on Bordeaux mixture. Because the product is a mixture rather than a single compound, its behavior depends on the copper sulfate to lime ratio. Treat the table as orientation, not as a specification.

Applications

Where a shade-matched granule is specified

Branded granule lines where both dust-free handling and shelf consistency matter.

Branded retail granule lines

Where a premium granule is sold on appearance as well as handling, shade consistency carries the brand.

  • Retail packs to your label artwork
  • Shade held across the contract
  • Retained reference per lot

Operator exposure reduction

The granule removes airborne dust at mixing and loading — the highest-exposure step, and the worst one on Bordeaux historically.

  • Dustiness specified per order
  • Attrition resistance held
  • No stock solutions, no sequencing

Counterfeit differentiation

A consistently held house shade on a granule is harder to copy than on a powder, and is one of the cheaper authenticity signals available.

  • Retained reference per lot
  • Size distribution fixed
  • Batch traceability to formulator

Dispersibility & tank behavior

Granules disintegrate on contact with water with no powder clumping, though mechanical agitation is still required.

  • Dispersibility specified
  • Suspensibility specified
  • Same-day use once mixed

Dormant-season disease control

Unchanged: peach leaf curl, shot hole, citrus brown rot, fire blight and walnut blight, in markets where registered.

  • FRAC M1 multi-site
  • Dormant timing is standard
  • Label claims are registrant-specific

Import & FIFRA coordination

A pesticide import needs a Notice of Arrival on EPA Form 3540-1, and US sale or use needs an EPA-registered product.

  • NOA coordination with your broker
  • UN 3077 documentation prepared
  • Registration remains yours
United States coverage

Delivered to US plants and ports

We ship blue Bordeaux mixture 20% WDG to nominated delivery points across the United States. The regions below are destinations we serve — Chelora Chemicals is a sourcing and supply partner, not a US manufacturer, and does not hold US stock.

Gulf Coast

The largest US chemical cluster, and the usual entry point for bulk consignments.

  • Houston & Galveston, TX
  • New Orleans & Baton Rouge, LA
  • Mobile, AL

Northeast

Container and bulk delivery into the mid-Atlantic and New England manufacturing belt.

  • Newark & Elizabeth, NJ
  • Philadelphia, PA
  • Boston, MA

Southeast

Port-side delivery for the Carolinas, Georgia and Florida processing plants.

  • Savannah, GA
  • Charleston, SC
  • Jacksonville, FL & Norfolk, VA

Midwest & Great Lakes

Inland rail and truck forwarding from the nearest coastal port to the industrial Midwest.

  • Chicago, IL
  • Detroit, MI
  • Cleveland & Columbus, OH

West Coast

Pacific routing for West Coast processors and formulators.

  • Los Angeles & Long Beach, CA
  • Oakland, CA
  • Seattle & Tacoma, WA

Southwest & Mountain

Inland delivery to interior states, forwarded from the Gulf or Pacific gateway.

  • Dallas–Fort Worth, TX
  • Phoenix, AZ
  • Denver, CO

Importing into the United States

Blue Bordeaux mixture 20% WDG is a TSCA-regulated chemical substance. Under TSCA section 13 the importer of record, or its authorized agent, must certify to US Customs and Border Protection that each shipment either complies with TSCA or is not subject to it. We confirm the substance's TSCA Inventory status and agree in writing who files that certification before the first consignment moves.

Which party carries that duty follows the Incoterm. On FOB, CFR or CIF terms it is usually the US buyer; on DDP terms it can be the seller or its agent. Safety data sheets and labels are supplied to OSHA's updated Hazard Communication Standard, and the UN 3077 Class 9 transport documentation is prepared before booking.

  • TSCA IMPORT CERTIFICATION
  • OSHA HAZCOM SDS & LABELS
  • UN 3077 · CLASS 9 · PG III
  • US CUSTOMS DOCUMENTATION
US delivery at a glance
ItemHow it works
Delivery pointsAny nominated US plant, terminal or port of discharge
Incoterms quotedFOB · CFR · CIF · DDP
Importer of recordAgreed in writing before the first shipment
TSCA certificationSection 13 positive certification filed at entry
DocumentationBatch COA, SDS, packing list, certificate of origin
Pack formats25 kg bags or retail packs

Note: regional coverage describes where we deliver, not where we hold inventory. Lead time depends on producer scheduling and ocean transit to your nominated US port — we confirm both in the quotation.

Buying from Chelora

How we supply blue Bordeaux mixture 20% WDG

Chelora Chemicals is a Bordeaux mixture supplier and sourcing partner, not a manufacturer. The thing to settle before quoting is the copper basis and the lime ratio, because CAS 8011-63-0 describes a mixture and says nothing about either.

We place your order with whichever qualified formulator best matches your specification, your price point and your delivery window, and settle the FIFRA and import position before booking.

We will also tell you when a fixed copper is the better product. If you are spraying into new growth, Bordeaux is the wrong tool — it is more phytotoxic than copper hydroxide or copper oxychloride, and that is a crop-damage risk rather than a preference.

  • Shade reference set on the granule, not on powder. A granule reflects light differently from loose powder of identical composition, so a powder reference will not transfer.
  • Attrition resistance does double duty. It protects the dust-free claim and the shade — crumbled granules read finer and bluer than the lot you approved.
  • Size distribution fixed alongside shade. It moves perceived color independently of composition.
  • Lime ratio fixed as part of the shade specification. It drives color and buffers phytotoxicity, so it cannot float.
  • Second source shade-qualified on granules in advance. Qualifying during a supply interruption is too late.
  • Honest advice on whether you need it. If the color is not exposed in your end use, we will quote the standard WDG instead.
Packing & logistics

Bagged or in retail packs

25 kg bags, bulk bags or retail packs — all to UN 3077 marking and labeling requirements.

Bags

25 kg poly-lined bags

Moisture-barrier bags on stretch-wrapped pallets, UN-marked, the standard commercial unit.

Retail packs

1 kg · 5 kg sealed packs

Small sealed packs in cartons to your approved label artwork where you hold the registration.

FIBC

500–1,000 kg bulk bags

Liner-fitted bulk bags for repacking operations and large-scale distribution.

Drums

Fiber drums

Sealed fiber drums where extra moisture protection or extended storage is needed.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with dangerous goods documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for suspension and crop safety trials before a commercial order.

Safety, storage & handling

Class 9, corrosive and phytotoxic — all three matter

Bordeaux carries three separate cautions that the fixed coppers do not all share: it is very toxic to aquatic life, which drives the Class 9 transport classification; it is highly corrosive to spray equipment; and it is more phytotoxic than the fixed coppers. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Warning

Classified hazards

  • H302Harmful if swallowed.
  • H315Causes skin irritation.
  • H318Causes serious eye damage.
  • H410Very toxic to aquatic life with long lasting effects.

Three practical cautions from agricultural extension guidance. Phytotoxicity: applying Bordeaux to newly growing leaves can injure new growth, which is why it is principally a dormant-season material. Equipment corrosion: it is highly corrosive, and guidance is to rinse spray equipment at least three times with a little vinegar added to neutralize the high-pH residue. Same-day use: once mixed it begins losing effectiveness immediately, and no product form changes that. Dry ingredients also need a tank with mechanical agitation. On US registration the ordinary FIFRA rule applies — the product must itself be EPA-registered for sale or use here, that registration sits with the registrant and never with a supplier, and imports require a Notice of Arrival, EPA Form 3540-1, filed with Customs.

Storage

Store in sealed, moisture-barrier packaging in a cool, dry, well-ventilated area away from food, seed and feedstuffs. Keep dry: the blend cakes if it takes up moisture, and the lime fraction carbonates on exposure to air, which changes the material over time. Bunded or contained storage is advised because of the aquatic hazard.

Handling

Handle with dust control, impervious gloves and tight-fitting eye protection; the material causes serious eye damage and is harmful if swallowed. Prevent any release to drains or watercourses. Follow the exposure controls set out in the batch SDS.

Transport

Bordeaux mixture is classified as dangerous goods for transport on the basis of aquatic toxicity, normally shipped as UN 3077, Environmentally hazardous substance, solid, n.o.s., Class 9, Packing Group III. Marked and labeled packaging, a dangerous goods declaration and compliant documentation are required. We confirm and document the classification for your specific grade, packaging and destination before booking.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Copper basis, copper sulfate to lime ratio, shade where specified, and formulation parameters confirmed before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS, FIFRA position and UN 3077 dangerous goods paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

Holding a shade through the granulator

The blend is made the same way as any Bordeaux: copper sulfate and hydrated lime combined under control, with the copper sulfate grade, the lime ratio and the fineness setting the shade. Those three are the same variables that govern color in the powder grades.

Granulation then adds variables the powder does not have. The blend is agglomerated with a binder into free-flowing granules, and the granule surface, the size distribution and the binder itself all affect how the color reads. A granule reflects light differently from a loose powder of the same composition, so a shade reference set on powder will not transfer — the reference has to be set on the granule as it will be supplied.

The last variable is attrition, and it is the one that catches people. Granules weak enough to crumble in transit present a finer, more light-scattering surface on arrival than the lot that was approved. So on this grade attrition resistance does double duty: it protects the dust-free claim the granule is bought for, and it protects the shade. Both are specified, and both are checked on the granule as supplied.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Formulation typeWater dispersible granule — WDG
Declared basisCopper expressed as metal
Shade drivers, blendGrade, lime ratio, fineness
Shade drivers, granuleSurface, size distribution, binder
Hidden shade riskAttrition back toward powder
How to specifyReference sample set on the granule
Frequently asked

Blue Bordeaux 20% WDG, answered

Why is shade harder to hold in a granule than a powder?
Because granulation adds variables. In a powder, color follows composition and fineness. In a granule it also follows the granule surface, the size distribution and the binder, so two lots of identical composition can read differently. A granule reflects light differently from a loose powder, which is why a shade reference set on powder does not transfer and has to be set on the granule as supplied.
How does attrition affect the shade?
Granules that crumble back toward powder in transit present a finer, more light-scattering surface than the lot you approved, so they read differently on arrival. That makes attrition resistance a shade specification on this grade as well as a dust one - the same parameter protects you from both problems, which is why we specify it and check it on the granule as supplied.
Is blue Bordeaux a different chemistry?
No. It is the same copper sulfate and lime mixture at CAS 8011-63-0, the same 20% copper expressed as metal, the same FRAC M1 multi-site contact action. Bordeaux is blue to begin with - famously so. What a shade specification buys is consistency of depth and cast between lots, not a color the standard product lacks.
What drives the shade in the blend itself?
Three things: the copper sulfate grade and source, the copper sulfate to lime ratio, which decides how far the precipitation reaction is taken, and the fineness of the blend. Unlike copper oxychloride there is no crystal-polymorph difference here, because Bordeaux is a mixture rather than a crystalline compound.
Is there an industry standard for the blue?
No. There is no published numeric color standard for Bordeaux mixture, so any supplier quoting one is applying a house standard. The only reliable method is a retained physical reference sample, set on the granule and matched lot to lot.
What does the 20% mean?
Copper expressed as metal, the convention across the copper fungicide category and on FAO specifications and US labels. Copper sulfate pentahydrate is 25.45% copper, so 20% copper as metal needs roughly 79% copper sulfate pentahydrate with about 18% hydrated lime. CAS 8011-63-0 identifies the mixture but says nothing about strength.
Does it still need same-day use?
Yes. Once Bordeaux is mixed with water it begins losing effectiveness, and the standing guidance is to use it the same day. That is a property of the chemistry rather than of the product form, so neither granulation nor shade specification changes it. Mechanical agitation in the tank is still required.
Is it still phytotoxic and corrosive?
Yes to both, and shade does not alter either. Bordeaux is more phytotoxic than the fixed coppers, which is why it is principally a dormant-season material and should not be sprayed into new growth. It is also highly corrosive to equipment, with extension guidance recommending at least three rinses with a little vinegar added to neutralize the high-pH residue.
Is it dangerous goods to ship?
Yes. Bordeaux mixture is very toxic to aquatic life with long-lasting effects, which makes it UN 3077, Environmentally hazardous substance solid n.o.s., Class 9, Packing Group III. Neither the granule form nor the shade changes the classification.
Do you supply blue Bordeaux 20% WDG in the United States?
Yes, to registrants, repackers, distributors and ports across the United States, including the Gulf Coast, Northeast, Southeast, Midwest, West Coast and Southwest. Chelora Chemicals is a sourcing and supply partner rather than a US manufacturer or registrant, so material is placed with a qualified formulator able to hold your shade reference on the granule.
Ready to order?

Get a quote on blue Bordeaux mixture 20% WDG

Ask us for trial granules so you can set the shade reference on the granule itself rather than on powder — then send the copper basis, lime ratio, attrition and dustiness specification, pack format and US delivery point.

Emailsource@cheloragroup.com
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Delivering toAll United States regions
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