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Copper Chemicals

Cuprous Chloride Powder CuCl · powder · CAS 7758-89-6

CAS No.7758-89-6

Bought for surface area, and limited by it. The powder dissolves and reacts faster than the granule — and oxidizes faster for exactly the same reason.

Chelora Chemicals is a cuprous chloride powder supplier and sourcing partner serving fine chemical, catalyst and synthesis buyers across the United States, with airtight packaging and a batch COA on every consignment.

  • 64.2% Cu THEORETICAL
  • POWDER — HIGH SURFACE
  • FAST DISSOLVING
  • WHITE = IN SPEC
  • UN 3077 CLASS 9
  • HS 2827 39
Product Identity Available to order
CAS Number
7758-89-6
Chemical name
Copper(I) chloride
Molecular formula
CuCl
Molecular weight
99.00 g/mol
Copper as Cu (theoretical)
64.2%
Physical form
Powder
Appearance
White — green indicates oxidation
Transport
UN 3077 · Class 9 · PG III
HS Code
2827 39

Note: white is the specification; green is the failure. Pure copper(I) chloride is a white solid. Impure or air-exposed material looks green, because the copper(I) has gone to copper(II) chloride — and in water it disproportionates outright, 2 CuCl → Cu + CuCl₂. So color on this product is not cosmetic: a green cast means part of your copper has changed oxidation state, and no total-copper assay will show it, because the copper is all still there.

64.2%Copper as Cu
99.00g/mol molecular weight
FastDissolution in HCl
WhiteIn-spec color
Where it sits

The reactive form of an unstable state

Copper(I) is an intermediate oxidation state. The powder gives you the most access to it — and the shortest window.

Copper(II) sourceCupric Chloride Dihydrate10125-13-0 ReductionTo the copper(I) state This productCuprous Chloride Powder7758-89-6 Into solutionDissolves readily in concentrated HCl DownstreamSandmeyer · catalysis · oxychloride manufacture

Why it matters: surface area cuts both ways — the powder reaches the reaction faster and the air faster, so it is bought to be used, not to be stored

Product overview

When you want the surface area

Cuprous chloride powder is the same compound as the granular grade — white CuCl at 64.2% copper, sparingly soluble in water but dissolving readily in concentrated hydrochloric acid. What differs is particle size, and with it the amount of exposed surface.

That makes the powder the grade for reaction rate. In Sandmeyer chemistry, where an arenediazonium salt is treated with CuCl to give an aryl chloride, and in Gattermann–Koch benzaldehyde synthesis, the reagent needs to be available fast. The same applies to catalyst preparation and to dissolution into acid. The cost is shelf life: oxidation also happens at the surface, so the powder greens faster once air reaches it. Buy it to use, not to hold.

When the powder is the right choice

  • Reaction rate matters. Sandmeyer, Gattermann–Koch and catalyst preparation all want fast availability.
  • Dissolution into acid. More surface means it goes into concentrated HCl faster.
  • Short time between opening and use. The powder rewards quick turnover and punishes storage.
  • The granular grade, if it will sit in stock: cuprous chloride granules.

Handling character

Cuprous chloride is air-sensitive and a Class 9 dangerous good. Full detail is in the Safety section below.

Typical powder specification
ParameterTypical value
AppearanceWhite powder
Assay as CuClPer agreed specification
Copper as Cu64.2% theoretical
Copper(II) contentPer agreed specification — the real test
Particle sizePer agreed sieve specification
Insolubles in HClPer agreed specification

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateWhite solid; green if oxidized
Molecular weight99.00 g/mol
Copper as Cu, theoretical64.2%
Melting point423 °C
Boiling point1,490 °C
Water solubility≈ 0.0047 g per 100 mL at 20 °C
In concentrated HClDissolves readily

Physical constants compiled from public reference data for CAS 7758-89-6 and rounded for readability. Both size grades share the same chemistry and assay; they differ in surface area, which governs both reaction rate and rate of oxidation. Treat the table as orientation, not as a specification.

Applications

Where US industry uses cuprous chloride

Sandmeyer chemistry, catalysis, fine synthesis and CO recovery.

Sandmeyer & Gattermann–Koch chemistry

Treating an arenediazonium salt with CuCl gives an aryl chloride, a reaction of wide scope and generally good yields.

  • Low copper(II) specified
  • Fast dissolution in HCl
  • Sealed small packs

Catalysis & polymerization

A catalyst in atom transfer radical polymerization and in Grignard 1,4-additions to unsaturated ketones.

  • Surface activity specified
  • Documented impurity profile
  • Airtight packaging

Fine chemical & laboratory synthesis

Where the reagent is weighed, charged and consumed quickly, the powder is the convenient form.

  • Reagent documentation on request
  • Small sealed packs
  • Retained sample held

Carbon monoxide separation

Its affinity for CO, with aluminum chloride, is used industrially to separate and recover carbon monoxide.

  • High surface activity
  • Consistent particle size
  • Technical desk review on request

Copper oxychloride manufacture

Aqueous cuprous chloride is generated and air-oxidized to copper oxychloride, the compound’s largest single outlet.

Import & compliance coordination

Industrial and catalytic uses take the ordinary import route; any pesticidal use does not.

  • End use confirmed before quoting
  • UN 3077 documentation prepared
  • Broker coordination on request
United States coverage

Delivered to US plants and ports

We ship cuprous chloride powder to nominated delivery points across the United States. The regions below are destinations we serve — Chelora Chemicals is a sourcing and supply partner, not a US manufacturer, and does not hold US stock.

Gulf Coast

The largest US chemical cluster, and the usual entry point for bulk consignments.

  • Houston & Galveston, TX
  • New Orleans & Baton Rouge, LA
  • Mobile, AL

Northeast

Container and bulk delivery into the mid-Atlantic and New England manufacturing belt.

  • Newark & Elizabeth, NJ
  • Philadelphia, PA
  • Boston, MA

Southeast

Port-side delivery for the Carolinas, Georgia and Florida processing plants.

  • Savannah, GA
  • Charleston, SC
  • Jacksonville, FL & Norfolk, VA

Midwest & Great Lakes

Inland rail and truck forwarding from the nearest coastal port to the industrial Midwest.

  • Chicago, IL
  • Detroit, MI
  • Cleveland & Columbus, OH

West Coast

Pacific routing for West Coast processors and formulators.

  • Los Angeles & Long Beach, CA
  • Oakland, CA
  • Seattle & Tacoma, WA

Southwest & Mountain

Inland delivery to interior states, forwarded from the Gulf or Pacific gateway.

  • Dallas–Fort Worth, TX
  • Phoenix, AZ
  • Denver, CO

Importing into the United States

Cuprous chloride powder is a TSCA-regulated chemical substance. Under TSCA section 13 the importer of record, or its authorized agent, must certify to US Customs and Border Protection that each shipment either complies with TSCA or is not subject to it. We confirm the substance's TSCA Inventory status and agree in writing who files that certification before the first consignment moves.

Which party carries that duty follows the Incoterm. On FOB, CFR or CIF terms it is usually the US buyer; on DDP terms it can be the seller or its agent. Safety data sheets and labels are supplied to OSHA's updated Hazard Communication Standard, and the UN 3077 Class 9 transport documentation is prepared before booking.

  • TSCA IMPORT CERTIFICATION
  • OSHA HAZCOM SDS & LABELS
  • UN 3077 · CLASS 9 · PG III
  • US CUSTOMS DOCUMENTATION
US delivery at a glance
ItemHow it works
Delivery pointsAny nominated US plant, terminal or port of discharge
Incoterms quotedFOB · CFR · CIF · DDP
Importer of recordAgreed in writing before the first shipment
TSCA certificationSection 13 positive certification filed at entry
DocumentationBatch COA, SDS, packing list, certificate of origin
Pack formats25 kg airtight drums

Note: regional coverage describes where we deliver, not where we hold inventory. Lead time depends on producer scheduling and ocean transit to your nominated US port — we confirm both in the quotation.

Buying from Chelora

How we supply cuprous chloride powder

Chelora Chemicals is a cuprous chloride supplier and sourcing partner, not a manufacturer. On the powder the binding constraint is time between opening and use — the same surface area you are paying for is what lets air at it.

We place your order with whichever qualified producer best matches your copper(II) limit and particle size, your price point and your delivery window, and confirm US import requirements before booking.

We will also tell you when the granular grade is the right buy. If the material will sit in stock or be drawn down slowly, granules will still be white when you reach the bottom of the drum.

  • Copper(II) content specified, not just total copper. Oxidation is the failure mode and it is invisible in a total-copper assay, because the copper is all still there.
  • Pack size matched to your draw-down rate. On a powder, a part-used drum is a degrading drum — smaller packs often cost less overall than waste.
  • Airtight packaging as standard. Air exposure degrades this product faster in powder form than in any other.
  • Particle size agreed up front. It governs reaction rate and shelf life together, and the two pull against each other.
  • We will steer you to granules where that is right. For stock held over time, the granular grade keeps better.
  • UN 3077 documentation prepared before booking. Class 9 on aquatic toxicity grounds; the paperwork is not optional.
Packing & logistics

Sealed in the size you will finish

25 kg airtight drums or smaller sealed packs — on a powder, pack size is a shelf-life decision.

Drums

25 kg airtight plastic drums

Sealed airtight drums, the default for an air-sensitive copper(I) compound.

Small sealed packs

1 kg · 5 kg units

Smaller sealed units so a part-used pack does not sit oxidizing between campaigns.

Bags

25 kg foil-lined bags

Barrier-lined sealed bags where drum handling is not wanted.

FIBC

500–1,000 kg bulk bags

Liner-fitted bulk bags for high-volume operations with fast turnover.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with dangerous goods documentation filed before booking.

Small trial packs

Trial / sample quantities

Small sealed packs dispatched for reaction and dissolution trials before a commercial order.

Safety, storage & handling

A Class 9 dangerous good — and air-sensitive

Cuprous chloride is harmful by ingestion and irritating to skin and eyes, and it is very toxic to aquatic life with long-lasting effects — which is what makes it a Class 9 dangerous good. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Warning

Classified hazards

  • H302Harmful if swallowed.
  • H315Causes skin irritation.
  • H319Causes serious eye irritation.
  • H410Very toxic to aquatic life with long lasting effects.

End use decides the import route. These copper compounds have industrial, catalytic, feed and in some cases pesticidal applications, and they do not all follow the same path into the United States. Where material is destined for a pesticidal use, the import is a pesticide import: it requires a Notice of Arrival, EPA Form 3540-1, filed with Customs, and any product sold or applied here must itself be EPA-registered under FIFRA, with that registration held by the registrant and never by a raw material supplier. For catalyst, electronics, metallurgical or other industrial use a different route applies, and feed use is a separate regulatory question again. Tell us the end use before we quote.

Storage

Store in sealed, airtight, moisture-barrier packaging in a cool, dry place, away from oxidizers and strong acids. Air is the enemy here: copper(I) oxidizes to copper(II) and the material greens. Keep packs closed, use opened packs promptly, and do not decant into open containers for storage. Bunded or contained storage is advised because of the aquatic hazard.

Handling

Handle with dust control, gloves and eye protection; the material is harmful if swallowed and irritates skin and eyes. Minimize the time packs are open — air exposure degrades the product as well as exposing the operator. Prevent any release to drains, watercourses or soil. Follow the controls in the batch SDS.

Transport

This material is classified as dangerous goods for transport on the basis of aquatic toxicity, normally shipped as UN 3077, Environmentally hazardous substance, solid, n.o.s., Class 9, Packing Group III. Marked and labeled packaging, a dangerous goods declaration and compliant documentation are required. We confirm and document the classification for your specific grade, packaging and destination before booking.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Copper assay, hydration or oxidation state, particle size, impurity limits and end use confirmed before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS, import position and UN 3077 paperwork checked by our desk before booking.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

Why form decides shelf life

Copper(I) chloride is made by reducing a copper(II) source, and the compound’s defining property is that copper(I) is an unstable oxidation state. Pure CuCl is white; air oxidizes it toward copper(II) chloride and it greens; in water it disproportionates outright into copper metal and copper(II) chloride.

Both the reaction you want and the degradation you do not happen at the particle surface. A powder presents far more surface per unit weight than a granule, so it dissolves faster into acid, reacts faster in a Sandmeyer coupling, and oxidizes faster in a part-used drum. There is no formulation trick that separates those — they are the same physics.

That is why pack size is a technical decision on this grade rather than a commercial one. A 25 kg drum opened for a 2 kg charge and resealed four times will not deliver the same material on the fourth charge as on the first. Where draw-down is slow, either buy granules or buy smaller packs.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Chemical familyCopper(I) chloride
Copper content64.2% — densest in this range
In-spec colorWhite; green means oxidized
Why powderSurface area — faster dissolution and reaction
Cost of thatFaster oxidation once air reaches it
Classic useSandmeyer aryl chloride synthesis
Frequently asked

Cuprous chloride powder, answered

What is the difference between the powder and the granules?
Surface area, and everything that follows. Both are the same compound at the same 64.2% copper. The powder presents far more surface per unit weight, so it dissolves into acid faster and reacts faster - but it also oxidizes faster once air reaches it. Granules have less surface, so they keep better but react more slowly.
Which grade should I buy?
Buy powder if the material goes into a reaction quickly and packs are finished soon after opening. Buy granules if it will sit in stock or be drawn down slowly. The decision is about turnover time rather than chemistry, because the same surface area that speeds the reaction also speeds the degradation.
Why does my powder look green?
Because copper(I) has oxidized to copper(II). Pure CuCl is white; green indicates copper(II) chloride is present. Air does it, and in water the compound disproportionates outright into copper metal and copper(II) chloride. A green cast is a quality failure, and it will not show in a total-copper assay because all the copper is still there.
How should I store an opened pack?
Resealed airtight, cool and dry, and used as soon as practical. A 25 kg drum opened repeatedly for small charges will not deliver the same material on the fourth charge as on the first. Where draw-down is slow, smaller sealed packs often cost less overall than the waste from a degrading drum - or switch to the granular grade.
What is it used for?
In the Sandmeyer reaction, treating an arenediazonium salt with CuCl to give an aryl chloride, a transformation of wide scope and generally good yields. Also as a co-catalyst in the Gattermann-Koch benzaldehyde synthesis, a catalyst in atom transfer radical polymerization and Grignard 1,4-additions, and with aluminum chloride to separate carbon monoxide. Industrially its largest outlet is making copper oxychloride.
How do I get it into solution?
Concentrated hydrochloric acid. Cuprous chloride is only sparingly soluble in water, about 0.0047 grams per 100 mL at 20 degrees Celsius, and in water it also disproportionates, so an aqueous suspension is not stable. The powder dissolves into concentrated HCl appreciably faster than the granular grade.
What should I specify besides total copper?
Copper(II) content, which is the real test. Oxidation is the failure mode on this product and a total-copper assay cannot detect it, because the copper is all still present and only its oxidation state has changed. We agree a copper(II) limit before quoting and have the plant state it on the certificate of analysis.
Is it hazardous?
It is harmful if swallowed and irritates skin and eyes, and it is very toxic to aquatic life with long-lasting effects. That aquatic classification makes it UN 3077, Environmentally hazardous substance solid n.o.s., Class 9, Packing Group III for transport. Dust control matters more on the powder than on the granules.
Do you supply cuprous chloride powder in the United States?
Yes. We deliver to fine chemical manufacturers, catalyst producers, laboratories and ports across the United States, including the Gulf Coast, Northeast, Southeast, Midwest, West Coast and Southwest. Chelora Chemicals is a sourcing and supply partner rather than a US manufacturer.
Do you manufacture this yourself?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with whichever qualified producer can hold your copper(II) limit and particle size, and hold a second source in reserve.
Ready to order?

Get a quote on cuprous chloride powder

Send us your copper(II) limit, particle size, and — importantly — how fast you will draw a pack down. On a powder that decides the pack size as much as your batch size does.

Emailsource@cheloragroup.com
Phone / WhatsApp+91 98191 11179
Delivering toAll United States regions
Response timeWithin one business day