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Foundry & Metallurgical Chemicals

Grain Refiner Tablets Titanium–Boron Salt Tablets for Aluminum

FormCompacted tablet

Grain refining without a rod feeder. A casthouse feeds Al-Ti-B rod into the launder; a foundry treating a crucible or ladle needs something it can weigh and plunge. Grain refiner tablets carry titanium and boron as salts that react with the molten aluminum and seed it with nuclei, so the casting freezes with finer, more even grains.

Chelora Chemicals is a grain refiner tablet supplier and sourcing partner serving aluminum foundries and die casters across the United States. We match the grade to your alloy and melt size, including sodium-free grades, with a batch COA and SDS on every consignment.

  • Ti–B SALT TABLETS
  • TiB₂ NUCLEI
  • FINER GRAIN
  • FOUNDRY Al-Si ALLOYS
  • SODIUM-FREE GRADES
  • COA & SDS
Product Identity Available to order
Product type
Grain refining tablet
Active salts
K₂TiF₆ · KBF₄
Nuclei formed in the melt
TiB₂ · TiAl₃
Metal
Aluminum casting alloys
Form
Compacted tablet
Grades
Standard · sodium-free
Application
Plunged or self-sinking
Dose
Per the producer's dosing guide
Documentation
Batch COA & SDS

Note: refine just before you pour. The nuclei settle over time, so the effect fades with holding. Treat, stir, and cast within the window the producer gives for the grade.

2Active salts: K₂TiF₆ and KBF₄
16919-27-0CAS, potassium fluorotitanate
14075-53-7CAS, potassium fluoroborate
TiB₂Nucleant formed in the melt
Where it sits

From salt tablet to fine grain

The tablet does not contain the nuclei. It makes them in the melt.

This productTi and B salts, compacted In the meltSalts react with aluminum FormedTiB₂ and TiAl₃ particles On freezingEach particle can seed a grain ResultFine, equiaxed grain structure

Why it matters: grain size decides feeding, hot tearing and properties. A coarse, columnar structure is harder to feed and more prone to cracking than a fine, equiaxed one

Product overview

What grain refiner tablets are and do

Grain refiner tablets are compacted titanium and boron salts, typically potassium fluorotitanate, K₂TiF₆, and potassium fluoroborate, KBF₄. On contact with molten aluminum the salts react, releasing titanium and boron into the melt as titanium diboride and titanium aluminide particles, with the spent salt floating off as a slag to be skimmed.

Those particles are the point. As the casting freezes, each one can act as a nucleus for a new grain, so the metal solidifies as many small, equiaxed grains instead of a few large, columnar ones. That improves feeding, reduces hot tearing and evens out mechanical properties. It is the same salt chemistry used to make Al-Ti-B master alloys, done in your crucible instead.

Tablets or master alloy?

  • Tablets suit crucible, ladle and small-furnace treatment, where a measured dose is plunged per melt.
  • Al-Ti-B rod suits continuous in-line feeding in casthouses and large casting lines.
  • Alloy matters. Silicon can reduce titanium-based refining, which is why grades differ in Ti:B balance.
  • Sodium-free grades for alloys where sodium is unwelcome.

Handling character

Grain refiner tablets must be dry and preheated before plunging. They react in the melt and release fluoride-bearing fume. Details in the Safety section.

What the specification controls
ParameterTypical value
Titanium contentPer grade
Boron contentPer grade
SodiumStandard or sodium-free grade
Tablet weightPer agreed specification
MoistureKept low; moisture-barrier pack
Dosing guideSupplied with the grade

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical formCompacted tablet
Active saltsK₂TiF₆ · KBF₄
Reaction productTiB₂ and TiAl₃ particles
By-productFluoride salt slag, skimmed
Effect fadesYes — particles settle with holding
Moisture sensitivityStore sealed and dry
AlternativeAl-Ti-B master alloy rod or waffle

CAS numbers are for the two active salts most commonly used. Titanium and boron content, tablet weight and dose are grade-specific and stated on the producer's COA and dosing guide. Treat the table as orientation, not as a specification.

Applications

Where grain refiner tablets are used

Foundry treatment of aluminum casting alloys, melt by melt.

Sand & permanent mold

Crucible and ladle treatment of aluminum-silicon casting alloys for better feeding and fewer hot tears.

  • Tablet size matched to melt
  • Dosing guide supplied
  • Batch COA

Die casting

Holding furnace and ladle treatment where grain structure affects soundness and properties.

  • Sodium-free options
  • Consistent tablet weight
  • Batch traceability

Alloy-matched grades

Silicon content changes how titanium-based refining performs, so the Ti:B balance is matched to the alloy.

  • Alloy reviewed before quoting
  • Grade options compared
  • Technical desk review

Combined treatment

Used alongside degassing and cleaning in a set melt-treatment sequence.

Moving from rod to tablets

Smaller lines that have no feeder can refine by tablet with a weighed dose.

Scheduled supply

Melt treatment runs every shift, so steady call-off supply matters more than spot price.

  • Annual contracts with call-off
  • Price held across the contract
  • Second source held in reserve
United States coverage

Delivered to US plants and ports

We ship grain refiner tablets to nominated delivery points across the United States. The regions below are destinations we serve — Chelora Chemicals is a sourcing and supply partner, not a US manufacturer, and does not hold US stock.

Gulf Coast

The largest US chemical cluster, and the usual entry point for bulk consignments.

  • Houston & Galveston, TX
  • New Orleans & Baton Rouge, LA
  • Mobile, AL

Northeast

Container and bulk delivery into the mid-Atlantic and New England manufacturing belt.

  • Newark & Elizabeth, NJ
  • Philadelphia, PA
  • Boston, MA

Southeast

Port-side delivery for the Carolinas, Georgia and Florida processing plants.

  • Savannah, GA
  • Charleston, SC
  • Jacksonville, FL & Norfolk, VA

Midwest & Great Lakes

Inland rail and truck forwarding from the nearest coastal port to the industrial Midwest.

  • Chicago, IL
  • Detroit, MI
  • Cleveland & Columbus, OH

West Coast

Pacific routing for West Coast processors and formulators.

  • Los Angeles & Long Beach, CA
  • Oakland, CA
  • Seattle & Tacoma, WA

Southwest & Mountain

Inland delivery to interior states, forwarded from the Gulf or Pacific gateway.

  • Dallas–Fort Worth, TX
  • Phoenix, AZ
  • Denver, CO

Importing into the United States

A grain refiner tablet is a chemical mixture, so TSCA looks at each component rather than the product name. Under TSCA section 13 the importer of record, or its authorized agent, must certify to US Customs and Border Protection that each shipment either complies with TSCA or is not subject to it. We confirm the Inventory status of every component with the producer and agree in writing who files that certification before the first consignment moves.

Which party carries that duty follows the Incoterm. On FOB, CFR or CIF terms it is usually the US buyer; on DDP terms it can be the seller or its agent. Safety data sheets and labels are supplied to OSHA's updated Hazard Communication Standard, and the grade-specific transport transport documentation is prepared before booking.

  • TSCA IMPORT CERTIFICATION
  • OSHA HAZCOM SDS & LABELS
  • GRADE-SPECIFIC TRANSPORT CLASS
  • US CUSTOMS DOCUMENTATION
US delivery at a glance
ItemHow it works
Delivery pointsAny nominated US plant, terminal or port of discharge
Incoterms quotedFOB · CFR · CIF · DDP
Importer of recordAgreed in writing before the first shipment
TSCA certificationSection 13 positive certification filed at entry
DocumentationBatch COA, SDS, packing list, certificate of origin
Pack formatsSealed tablet packs in cartons or drums

Note: regional coverage describes where we deliver, not where we hold inventory. Lead time depends on producer scheduling and ocean transit to your nominated US port — we confirm both in the quotation.

Buying from Chelora

How we supply grain refiner tablets

Chelora Chemicals is a grain refiner tablet supplier and sourcing partner, not a manufacturer. We place your order with a qualified producer whose grade fits your alloy, your melt size and your treatment practice.

We ask about the alloy first. Silicon content affects how titanium-based refining performs, and some alloys need a sodium-free grade, so the right tablet for a general casting alloy is not automatically right for yours.

Then dose and timing. Tablet weight is matched to melt weight, and because the refining effect fades as the particles settle, we send the producer's guidance on when to treat relative to pouring.

  • Alloy reviewed before quoting. Ti:B balance and sodium content matched to your alloy.
  • Tablet size matched to your melt. A weighed dose per crucible or ladle.
  • Dosing and timing guide with the grade. Including how long the effect holds.
  • Moisture-barrier packaging. A damp tablet is a safety hazard and a poor refiner.
  • Rod and tablets from one desk. If you outgrow tablets, Al-Ti-B rod is quoted too.
  • Batch traceability to the producing plant. Full chain of custody documentation on request.
Packing & logistics

Sealed, dry and sized to your melt

Tablets in moisture-barrier packs, cartoned or drummed, with full documentation.

Bags

25 kg moisture-barrier bags

Poly-lined bags, the standard unit for flux products.

Drums

Lined drums

Lined, resealable drums for use from the container at the furnace.

Tablet cartons

Sealed packs in cartons

Tablet grades sealed in moisture-barrier packs and cartoned.

Trial packs

Small trial quantities

Small packs for trial on your alloy before a commercial order.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to.

Call-off contracts

Scheduled deliveries

Annual volume released against your melt schedule.

Safety, storage & handling

Fluoride salts going into molten metal

Grain refiner tablets are fluoride salts that react in molten aluminum, so the hazards are fluoride-bearing fume at the melt, moisture — any water reaching molten aluminum can cause a violent steam eruption — and the toxicity of the salts themselves. The summary below is orientation only; the safety data sheet supplied with your batch is the authoritative document.

GHS Signal word: Grade-dependent

Classified hazards

  • F⁻Fluoride salts (K₂TiF₆, KBF₄): harmful if swallowed or inhaled; classification per SDS.
  • FumeFluoride-bearing fume at the melt: use local exhaust ventilation.
  • H₂ODamp or cold tablets in molten aluminum: risk of violent steam eruption.
  • PPEFace shield, heat-resistant gloves and protective clothing when plunging.
  • SDSGrade-specific GHS classification in the batch SDS.

The US air rule worth knowing. EPA's secondary aluminum NESHAP, 40 CFR Part 63 Subpart RRR, defines reactive fluxing as any gas, liquid or solid flux, other than cover flux, that results in a hazardous air pollutant emission, and it defines cover flux as salt added to the melt surface without surface agitation to prevent oxidation. Foundries, die casters and extruders melting only clean charge, customer returns or internal scrap are outside the definition of a secondary aluminum production facility. Whether your fluxing practice brings you inside the rule is a determination for you and your permitting authority; we supply the composition data you need to make it.

Storage

Store in sealed original packs in a dry, covered area, off the floor and away from food and feedstuffs. Keep packs closed until use; tablets that have taken up moisture should not be used.

Handling

Preheat the tablet and the plunger above the melt to drive off moisture, plunge steadily and hold until the reaction ends, then stir and skim the slag. Wear a face shield, heat-resistant gloves and protective clothing, and use local exhaust ventilation at the melt. Follow the batch SDS and the producer's application guide.

Transport

Transport classification is set by the formulation; fluoride content can bring a grade into a toxic class. We confirm and document the classification for your grade, packaging and destination before booking.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Alloy family, melt temperature, application method and the grade chemistry confirmed against your process before the order is placed.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS, TSCA position and transport classification checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

Why the refining effect fades

A grain refiner works by putting solid particles into a liquid, and solid particles that are denser than the liquid do what you would expect: they settle. Titanium diboride is markedly denser than molten aluminum, so from the moment the tablet reacts, the population of effective nuclei in the upper part of the melt starts to fall.

That is why foundries talk about fade. Treat too early, hold too long, or pour from a melt that has sat undisturbed, and the casting sees fewer nuclei than the dose suggests. Stirring before pouring redistributes particles that have not yet agglomerated; it does not fully restore them.

The practical rule is simple: treat close to pouring, stir before you cast, and follow the producer's guidance for the grade on how long the effect holds. It is also why a measured tablet per melt suits batch foundries, while continuous casting lines feed rod right at the mold.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Product familyAluminum grain refiner
Active saltsK₂TiF₆ · KBF₄
NucleiTiB₂ · TiAl₃ formed in the melt
ApplicationPlunged or self-sinking tablet
FadeEffect falls with holding time
AlternativeAl-Ti-B rod or waffle
Frequently asked

Grain refiner tablets, answered

What do grain refiner tablets do?
They put nucleating particles into molten aluminum so the casting solidifies as many small, equiaxed grains instead of a few large, columnar ones. A finer grain structure improves feeding, reduces hot tearing and evens out mechanical properties.
What are grain refiner tablets made of?
Typically compacted titanium and boron salts - potassium fluorotitanate, K2TiF6, CAS 16919-27-0, and potassium fluoroborate, KBF4, CAS 14075-53-7. The salts react with the aluminum to form titanium diboride and titanium aluminide particles, and the spent salt floats off as a slag to be skimmed. Exact Ti and B content varies by grade.
How are grain refiner tablets used?
Preheat the tablet and plunger to drive off moisture, plunge to the bottom of the melt and hold until the reaction ends, then stir and skim. Some grades are self-sinking and need no plunging. Dose and timing come from the producer's guide for the grade.
Why does the grain refining effect fade?
Titanium diboride particles are denser than molten aluminum and settle over time, so the number of effective nuclei in the metal you pour falls with holding. Treat close to pouring and stir before casting.
Should I use tablets or Al-Ti-B rod?
Tablets suit batch treatment in crucibles, ladles and small furnaces, where a measured dose is plunged per melt. Al-Ti-B rod suits continuous in-line feeding in casthouses and high-volume lines. We supply both and can quote them side by side.
Do grain refiner tablets work in aluminum-silicon alloys?
Yes, they are widely used in foundry aluminum-silicon alloys. Silicon can reduce the efficiency of titanium-based refining, which is why grades differ in their titanium-to-boron balance. Tell us the alloy and we will match the grade.
Are sodium-free grain refiner tablets available?
Yes. Sodium-free grades exist for alloys where sodium is unwelcome, such as aluminum-magnesium alloys and phosphorus-refined hypereutectic aluminum-silicon. We specify them where the alloy calls for it.
What safety precautions apply?
The tablets are fluoride salts that react in molten metal. Keep them dry and preheat before plunging, because moisture reaching molten aluminum can cause a violent steam eruption. Use local exhaust ventilation for the fluoride-bearing fume and wear a face shield, heat-resistant gloves and protective clothing. The batch SDS gives the classification.
How should grain refiner tablets be stored?
Sealed in their original packs, in a dry covered area, off the floor and away from food and feedstuffs. Keep packs closed until use; a tablet that has taken up moisture should not be used.
Do you manufacture grain refiner tablets?
No - Chelora Chemicals is a supplier and sourcing partner, not a manufacturer. We place your order with a qualified producer whose grade fits your alloy and melt practice, and deliver to your nominated US plant or port with a batch COA and SDS.
Ready to order?

Get a quote on grain refiner tablets

Tell us your alloy, melt size per treatment and how long metal is held before pouring. We will match a grade and tablet size, send the dosing and timing guide, and quote Al-Ti-B rod alongside if you are comparing routes.

Emailsource@cheloragroup.com
Phone / WhatsApp+91 98191 11179
Delivering toAll United States regions
Response timeWithin one business day