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Crop Protection & Copper Chemicals

Bordeaux Mixture 20% WDG 20% Cu as metal · WDG · CAS 8011-63-0

CAS No.8011-63-0

The furthest a Bordeaux product gets from the thing that made Bordeaux dangerous — no stock solutions, no sequencing, and now no dust either.

Chelora Chemicals is a Bordeaux mixture 20% WDG supplier and sourcing partner serving registrants and distributors across the United States, with dispersibility, attrition and dustiness agreed before dispatch.

  • DUST-FREE GRANULE
  • 20% Cu AS METAL
  • DISPERSES ON CONTACT
  • FRAC M1
  • DORMANT SEASON
  • UN 3077 CLASS 9
Product Identity Available to order
CAS Number
8011-63-0
Formulation type
Water dispersible granule — WDG
Copper as Cu
20% w/w
Composition
Copper sulfate + hydrated lime
Copper sulfate basis
≈ 79% pentahydrate equivalent
FRAC group
M1 — multi-site contact
Appearance
Blue to blue-green granule
Transport
UN 3077 · Class 9 · PG III
HS Code
3808 92

Note: a WDG is judged on the granule, not just the copper. Three parameters exist here that have no equivalent on a powder: dustiness, attrition resistance — whether the granules survive handling without crumbling back to powder — and flowability. Attrition is the one most often left off a purchase order, and granules that crumble in transit hand you back the dust you paid to avoid. The 20% is copper expressed as metal, roughly 79% copper sulfate pentahydrate equivalent.

20%Copper as metal
WDGGranule — not powder
M1FRAC group
3077UN number
Where it sits

From field mix to dust-free granule

Each step in Bordeaux’s commercial history has removed a hazard. The granule removes the last one.

Copper sourceCopper sulfate Neutralizing agentHydrated lime — calcium hydroxide Milling & granulationBinder, dispersant, agglomeration This productBordeaux Mixture 20% WDG8011-63-0 ApplicationDisperses on contact with water

Why it matters: Bordeaux was always the most hazardous copper to prepare — stock solutions, lime, and a sequence that mattered. A granule is the opposite of all of that

Product overview

Why a granule suits Bordeaux particularly well

Bordeaux mixture 20% WDG carries the same active content as the 20% WP — 20% copper expressed as metal, the same copper sulfate and lime chemistry, the same FRAC M1 multi-site contact action. What differs is that the formulation is granulated, so it pours rather than puffs and the granules disintegrate on contact with water in the tank.

The case for a granule is stronger here than on any other copper. Bordeaux has always been the most hazardous copper to prepare: concentrated copper sulfate stock solution, hydrated lime, and a sequence that had to be right or the copper would not dissolve. The WP removed the stock solutions. The granule removes the dust at mixing and loading, which is the highest-exposure step left in the operation.

What a WDG specification controls that a WP does not

  • Dustiness. The reason the form exists — specified per order and verified on the granule as supplied.
  • Attrition resistance. Whether granules survive handling without crumbling back to powder.
  • Flowability. Decides measuring accuracy and how cleanly the pack empties for triple-rinse disposal.
  • The powder form for comparison: Bordeaux 20% WP.

Handling character

Bordeaux is a Class 9 dangerous good, corrosive to equipment and phytotoxic on new growth. Full detail is in the Safety section below.

Typical WDG formulation specification
ParameterTypical value
AppearanceBlue to blue-green free-flowing granule
Copper as Cu20% w/w ± tolerance
Copper sulfate to lime ratioPer agreed specification
Dispersibility & suspensibilityPer agreed specification
Dustiness & attrition resistancePer agreed specification
Flowability & wet sieve residuePer agreed specification

Important: the figures above are indicative of commercial material and are offered for planning only. The batch certificate of analysis is the governing document.

Physical & chemical properties
PropertyValue
Physical stateBlue to blue-green granule
NatureMixture, not a single compound
Water behaviorGranules disintegrate and disperse
Mode of actionMulti-site contact; FRAC M1
Tank stabilityUse the same day once mixed
RainfastnessLonger lasting than fixed coppers
EquipmentHighly corrosive; rinse thoroughly

Characteristics compiled from public agricultural extension guidance on Bordeaux mixture. Because the product is a mixture rather than a single compound, its behavior depends on the copper sulfate to lime ratio. Treat the table as orientation, not as a specification.

Applications

Where the granule form earns its premium

Operator safety, accurate measuring, and the same dormant-season programs.

Operator exposure reduction

Bordeaux was always the worst copper to prepare. A granule removes airborne dust at mixing and loading, the highest-exposure step left.

  • Dustiness specified per order
  • Attrition resistance held
  • No stock solutions, no sequencing

Dispersibility & tank behavior

Granules disintegrate on contact with water, so there is no powder clumping on tank fill — though mechanical agitation is still needed.

  • Dispersibility specified
  • Suspensibility specified
  • Mechanical agitation required

Dormant-season disease control

Unchanged from the WP: peach leaf curl, shot hole, bacterial blast and brown rot on citrus, fire blight and walnut blight.

  • FRAC M1 multi-site
  • Dormant timing is standard
  • Label claims are registrant-specific

Accurate measuring & clean packs

Free-flowing granules measure accurately and empty cleanly, leaving less residue for triple-rinse disposal.

  • Flowability specified
  • 1 kg and 5 kg retail packs
  • Artwork to your registrant label

Registrant & repacker supply

Bulk supply to registrants positioning a premium granule alongside a WP line.

  • 25 kg bags and bulk bags
  • Ratio held across the contract
  • Second formulator qualified

Import & FIFRA coordination

A pesticide import needs a Notice of Arrival on EPA Form 3540-1, and US sale or use needs an EPA-registered product.

  • NOA coordination with your broker
  • UN 3077 documentation prepared
  • Registration remains yours
United States coverage

Delivered to US plants and ports

We ship Bordeaux mixture 20% WDG to nominated delivery points across the United States. The regions below are destinations we serve — Chelora Chemicals is a sourcing and supply partner, not a US manufacturer, and does not hold US stock.

Gulf Coast

The largest US chemical cluster, and the usual entry point for bulk consignments.

  • Houston & Galveston, TX
  • New Orleans & Baton Rouge, LA
  • Mobile, AL

Northeast

Container and bulk delivery into the mid-Atlantic and New England manufacturing belt.

  • Newark & Elizabeth, NJ
  • Philadelphia, PA
  • Boston, MA

Southeast

Port-side delivery for the Carolinas, Georgia and Florida processing plants.

  • Savannah, GA
  • Charleston, SC
  • Jacksonville, FL & Norfolk, VA

Midwest & Great Lakes

Inland rail and truck forwarding from the nearest coastal port to the industrial Midwest.

  • Chicago, IL
  • Detroit, MI
  • Cleveland & Columbus, OH

West Coast

Pacific routing for West Coast processors and formulators.

  • Los Angeles & Long Beach, CA
  • Oakland, CA
  • Seattle & Tacoma, WA

Southwest & Mountain

Inland delivery to interior states, forwarded from the Gulf or Pacific gateway.

  • Dallas–Fort Worth, TX
  • Phoenix, AZ
  • Denver, CO

Importing into the United States

Bordeaux mixture 20% WDG is a TSCA-regulated chemical substance. Under TSCA section 13 the importer of record, or its authorized agent, must certify to US Customs and Border Protection that each shipment either complies with TSCA or is not subject to it. We confirm the substance's TSCA Inventory status and agree in writing who files that certification before the first consignment moves.

Which party carries that duty follows the Incoterm. On FOB, CFR or CIF terms it is usually the US buyer; on DDP terms it can be the seller or its agent. Safety data sheets and labels are supplied to OSHA's updated Hazard Communication Standard, and the UN 3077 Class 9 transport documentation is prepared before booking.

  • TSCA IMPORT CERTIFICATION
  • OSHA HAZCOM SDS & LABELS
  • UN 3077 · CLASS 9 · PG III
  • US CUSTOMS DOCUMENTATION
US delivery at a glance
ItemHow it works
Delivery pointsAny nominated US plant, terminal or port of discharge
Incoterms quotedFOB · CFR · CIF · DDP
Importer of recordAgreed in writing before the first shipment
TSCA certificationSection 13 positive certification filed at entry
DocumentationBatch COA, SDS, packing list, certificate of origin
Pack formats25 kg bags or retail packs

Note: regional coverage describes where we deliver, not where we hold inventory. Lead time depends on producer scheduling and ocean transit to your nominated US port — we confirm both in the quotation.

Buying from Chelora

How we supply Bordeaux mixture 20% WDG

Chelora Chemicals is a Bordeaux mixture supplier and sourcing partner, not a manufacturer. The thing to settle before quoting is the copper basis and the lime ratio, because CAS 8011-63-0 describes a mixture and says nothing about either.

We place your order with whichever qualified formulator best matches your specification, your price point and your delivery window, and settle the FIFRA and import position before booking.

We will also tell you when a fixed copper is the better product. If you are spraying into new growth, Bordeaux is the wrong tool — it is more phytotoxic than copper hydroxide or copper oxychloride, and that is a crop-damage risk rather than a preference.

  • Attrition resistance specified, not assumed. Granules that crumble in transit hand you back the dust problem you paid to avoid — and it is the parameter most often left off a purchase order.
  • Dustiness verified on the granule as supplied. The whole commercial case for a WDG rests on it, and on Bordeaux that case is stronger than on any other copper.
  • Dispersibility and suspensibility agreed up front. A granule strong enough to ship must still fall apart in the tank; the two pull against each other.
  • Copper basis stated as metal, with the arithmetic shown. 20% copper as Cu is roughly 79% copper sulfate pentahydrate.
  • Lime ratio agreed in writing. A 20% copper blend runs leaner on lime than a traditional 1:1 field mix, and lime is what buffers the phytotoxicity.
  • Same-day use made explicit. The granule fixes dust and preparation, not tank life.
Packing & logistics

Bagged or in retail packs

25 kg bags, bulk bags or retail packs — all to UN 3077 marking and labeling requirements.

Bags

25 kg poly-lined bags

Moisture-barrier bags on stretch-wrapped pallets, UN-marked, the standard commercial unit.

Retail packs

1 kg · 5 kg sealed packs

Small sealed packs in cartons to your approved label artwork where you hold the registration.

FIBC

500–1,000 kg bulk bags

Liner-fitted bulk bags for repacking operations and large-scale distribution.

Drums

Fiber drums

Sealed fiber drums where extra moisture protection or extended storage is needed.

FOB · CIF · CFR · DDP

Incoterms to suit you

Quoted on the Incoterm your purchasing team works to, with dangerous goods documentation filed before booking.

Small trial packs

Trial / sample quantities

Small packs dispatched for suspension and crop safety trials before a commercial order.

Safety, storage & handling

Class 9, corrosive and phytotoxic — all three matter

Bordeaux carries three separate cautions that the fixed coppers do not all share: it is very toxic to aquatic life, which drives the Class 9 transport classification; it is highly corrosive to spray equipment; and it is more phytotoxic than the fixed coppers. The summary below is orientation only — the safety data sheet supplied with your specific batch is the authoritative document.

GHS Signal word: Warning

Classified hazards

  • H302Harmful if swallowed.
  • H315Causes skin irritation.
  • H318Causes serious eye damage.
  • H410Very toxic to aquatic life with long lasting effects.

Three practical cautions from agricultural extension guidance. Phytotoxicity: applying Bordeaux to newly growing leaves can injure new growth, which is why it is principally a dormant-season material. Equipment corrosion: it is highly corrosive, and guidance is to rinse spray equipment at least three times with a little vinegar added to neutralize the high-pH residue. Same-day use: once mixed it begins losing effectiveness immediately, and no product form changes that. Dry ingredients also need a tank with mechanical agitation. On US registration the ordinary FIFRA rule applies — the product must itself be EPA-registered for sale or use here, that registration sits with the registrant and never with a supplier, and imports require a Notice of Arrival, EPA Form 3540-1, filed with Customs.

Storage

Store in sealed, moisture-barrier packaging in a cool, dry, well-ventilated area away from food, seed and feedstuffs. Keep dry: the blend cakes if it takes up moisture, and the lime fraction carbonates on exposure to air, which changes the material over time. Bunded or contained storage is advised because of the aquatic hazard.

Handling

Handle with dust control, impervious gloves and tight-fitting eye protection; the material causes serious eye damage and is harmful if swallowed. Prevent any release to drains or watercourses. Follow the exposure controls set out in the batch SDS.

Transport

Bordeaux mixture is classified as dangerous goods for transport on the basis of aquatic toxicity, normally shipped as UN 3077, Environmentally hazardous substance, solid, n.o.s., Class 9, Packing Group III. Marked and labeled packaging, a dangerous goods declaration and compliant documentation are required. We confirm and document the classification for your specific grade, packaging and destination before booking.

Quality assurance

Every batch, documented

We verify documentation before dispatch so there are no surprises at your incoming-goods bench.

Specification agreed

Copper basis, copper sulfate to lime ratio, shade where specified, and formulation parameters confirmed before order placement.

Producer batch testing

The producing plant tests each batch against the agreed specification before release.

Documentation review

COA, SDS, FIFRA position and UN 3077 dangerous goods paperwork checked by our desk before the shipment is booked.

Traceable dispatch

Each shipment is traceable to its producing batch, with full chain-of-custody records on request.

Production background

How a Bordeaux WDG is built

A Bordeaux water dispersible granule starts where the wettable powder does — copper sulfate and hydrated lime combined under control and milled with a wetting agent and dispersant. The extra step is granulation: the blend is agglomerated, usually by extrusion or fluid-bed granulation, into free-flowing granules held together by a binder.

The engineering problem is that the granule must be strong enough to survive handling and weak enough to fall apart in water. Too little binder and the granules attrit back to powder in transit, handing you the dust the form exists to remove. Too much and they sit in the tank undispersed. Dispersibility and attrition resistance pull against each other, which is why both are specified.

None of this changes the chemistry. The copper is declared as metal at 20%, roughly 79% copper sulfate pentahydrate equivalent; the mode of action is FRAC M1 multi-site contact; the material is still more phytotoxic than a fixed copper and still corrosive to equipment; and the mixed spray must still be used the same day.

We do not publish operating process parameters here; this is background only. Full technical documentation accompanies every shipment, and any process-specific detail you need is best confirmed directly with our technical desk.

Quick reference
Formulation typeWater dispersible granule — WDG
Declared basisCopper expressed as metal
Compound equivalent≈ 79% copper sulfate pentahydrate
Bought forDust reduction and handling, not efficacy
Granule-specific testsDustiness, attrition, flowability
What it does not fixSame-day tank life
Frequently asked

Bordeaux mixture 20% WDG, answered

What is the difference between the WDG and the WP?
Both deliver the same active at the same loading - 20% copper expressed as metal from the same copper sulfate and lime chemistry. A wettable powder is a fine dry powder that has to be wetted into the tank; a water dispersible granule is granulated so it pours rather than puffs, and the granules disintegrate on contact with water. The practical differences are dust, flow and measuring accuracy, not efficacy.
Why does the dust matter more on Bordeaux than on other coppers?
Because Bordeaux was always the most hazardous copper to handle. Traditional preparation meant concentrated copper sulfate stock solution and hydrated lime, mixed in a sequence that had to be right or the copper would not dissolve. The wettable powder removed the stock solutions; the granule removes the airborne dust at mixing and loading, which is the highest-exposure step left in the operation.
Which specification parameters matter on a WDG?
More than on a WP, because the granule itself has to perform. Dispersibility decides whether the granules break down in the tank; suspensibility decides how much stays dispersed; wet sieve residue decides nozzle behavior; and three parameters are specific to the granule form - dustiness, attrition resistance, which is whether granules survive handling without crumbling back to powder, and flowability. Limits are agreed per order rather than being universal.
Can the granules crumble back into powder?
Yes, and that is what attrition resistance measures. Granules that break down during transport, handling or repacking give you the dust problem you paid to avoid. It is the parameter most worth specifying on a WDG and the one most often left off a purchase order, so we agree it before quoting.
What does the 20% mean?
Copper expressed as metal, the convention across the copper fungicide category and on FAO specifications and US labels. Copper sulfate pentahydrate is 25.45% copper, so 20% copper as metal needs roughly 79% copper sulfate pentahydrate, with about 18% hydrated lime. CAS 8011-63-0 identifies the mixture but says nothing about strength, so the basis and the ratio are agreed in writing.
Does the granule last longer in the tank?
No. Once Bordeaux is mixed with water it begins losing effectiveness, and the standing guidance is to use it the same day. That is a property of the chemistry rather than of the product form, so granulation does not extend it. The tank also still needs mechanical agitation, since bypass agitator systems are usually inadequate.
Is it still phytotoxic and corrosive?
Yes to both - those come from the chemistry, not the form. Bordeaux is more phytotoxic than the fixed coppers, which is why it is principally a dormant-season material and should not be sprayed into new growth. It is also highly corrosive to equipment, and extension guidance recommends rinsing at least three times with a little vinegar added to neutralize the high-pH residue.
Is it dangerous goods to ship?
Yes. Bordeaux mixture is very toxic to aquatic life with long-lasting effects, which makes it UN 3077, Environmentally hazardous substance solid n.o.s., Class 9, Packing Group III. The granule form does not change the classification. Marked and labeled packaging and a dangerous goods declaration are required.
Can I sell or apply this in the United States?
Only if the specific product is EPA-registered. Under FIFRA a pesticide product must itself hold a registration for US sale or use, and that registration sits with the registrant, never with a supplier. An imported pesticide also requires a Notice of Arrival on EPA Form 3540-1 filed with Customs.
Do you supply Bordeaux mixture 20% WDG in the United States?
Yes, to registrants, repackers, distributors and ports across the United States, including the Gulf Coast, Northeast, Southeast, Midwest, West Coast and Southwest. Chelora Chemicals is a sourcing and supply partner rather than a US manufacturer or registrant, so material is placed with a qualified formulator and shipped to your nominated US delivery point.
Ready to order?

Get a quote on Bordeaux mixture 20% WDG

Send us your required copper basis, lime ratio, dispersibility, dustiness and attrition specification, pack format and US delivery point — and tell us whether you hold a product registration.

Emailsource@cheloragroup.com
Phone / WhatsApp+91 98191 11179
Delivering toAll United States regions
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